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ChemicalBook--->CAS DataBase List--->131379-39-0

131379-39-0

131379-39-0 Structure

131379-39-0 Structure
IdentificationBack Directory
[Name]

4-ETHOXY-4-OXOBUTYLZINC BROMIDE
[CAS]

131379-39-0
[Synonyms]

4-ETHOXY-4-OXOBUTYLZINC BROMIDE
3-(Ethoxycarbonyl)propylzinc bromide
(4-ethoxy-4-oxobutyl)zinc(II) broMide
4-ethoxy-4-oxobutylzinc bromide solution
4-Ethoxy-4-oxobutylzinc bromide solution 0.5 in THF
4-Ethoxy-4-oxobutylzinc broMide solution 0.5 M in THF
4-ETHOXY-4-OXOBUTYLZINC BROMIDE, 0.5MSOL UTION IN TETRAHYDROFURAN
3-(Ethoxycarbonyl)propylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
3-(Ethoxycarbonyl)propylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
[Molecular Formula]

C6H11BrO2Zn
[MDL Number]

MFCD00671977
[MOL File]

131379-39-0.mol
[Molecular Weight]

260.44
Chemical PropertiesBack Directory
[density ]

0.976 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
[Water Solubility ]

Reacts with water.
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07,GHS08,GHS02,GHS05
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H351-H225-H261-H302-H314-H318-H333
[Precautionary statements ]

P210-P223-P303+P361+P353-P405-P501a-P261-P281-P305+P351+P338
[Hazard Codes ]

F,Xn
[Risk Statements ]

14-19-22-36/37/38-40-36/37
[Safety Statements ]

16-26-33-36/37/39-45-36/37
[RIDADR ]

UN 3399 4.3/PG 2
[WGK Germany ]

1
[HazardClass ]

4.3
[HS Code ]

29319090
Hazard InformationBack Directory
[Uses]

4-Ethoxy-4-oxobutylzinc bromide can be used:
  • As an intermediate in one of the key synthetic steps for the preparation of acrylic acid derivatives as EP3 receptor antagonists.
  • As an intermediate in the final step of the total synthesis of a natural product mucosin.
  • As a substrate in the synthesis of multi-substituted haloalkenes by reacting with 1-haloalkenes via Negishi cross-coupling reaction.

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