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ChemicalBook--->CAS DataBase List--->1477-42-5

1477-42-5

1477-42-5 Structure

1477-42-5 Structure
IdentificationMore
[Name]

2-Amino-4-methylbenzothiazole
[CAS]

1477-42-5
[Synonyms]

2-AMINO-4-METHYLBENZOTHIAZOLE
4-METHYL-1,3-BENZOTHIAZOL-2-AMINE
4-methylbenzothiazol-2-ylamine
AURORA 18742
LABOTEST-BB LT00080789
2-amino-4-methyl-benzothiazol
4-Methyl-2-aminobenzothiazole
4-methyl-2-benzothiazolamin
4-Methyl-2-benzothiazolamine
Benzothiazole, 2-amino-4-methyl-
2-Benzothiazolamine,4-methyl-(9CI)
4-methyl-2-amimobenzothiazol
4-methyl-2-amimobenzothiagol
2-Imino-4-methyl-2,3-dihydrobenzothiazole
4-Methylbenzothiazol-2-amine
[EINECS(EC#)]

216-028-3
[Molecular Formula]

C8H8N2S
[MDL Number]

MFCD00005793
[Molecular Weight]

164.23
[MOL File]

1477-42-5.mol
Chemical PropertiesBack Directory
[Appearance]

OFF-WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER
[Melting point ]

137-139 °C (lit.)
[Boiling point ]

322.0±35.0 °C(Predicted)
[density ]

1.1724 (rough estimate)
[refractive index ]

1.5700 (estimate)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[pka]

pK1: 4.7(+1) (25°C)
[Water Solubility ]

<0.1 g/100 mL at 24 ºC
[Sensitive ]

Moisture Sensitive
[BRN ]

129346
[CAS DataBase Reference]

1477-42-5(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Benzothiazolamine, 4-methyl-(1477-42-5)
[EPA Substance Registry System]

1477-42-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

DL2275000
[TSCA ]

Yes
[HS Code ]

29342000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Chloroform-->Chlorine-->N-(2-Methylphenyl)thiourea-->2-AMINOBENZOTHIAZOLE HYDROCHLORIDE
[Preparation Products]

Tricyclazole-->4-Methyl-2-benzothiazolehydrazine-->Benzothiazole, 4-methyl- (7CI,8CI,9CI)-->BenzenaMine, 2,2'-dithiobis[6-Methyl-
Hazard InformationBack Directory
[General Description]

White powder.
[Reactivity Profile]

An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

This compound is sensitive to moisture. Insoluble in water.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits very toxic fumes of SOx and NOx.
[Fire Hazard]

Flash point data for this chemical are not available. 2-AMINO-4-METHYLBENZOTHIAZOLE(1477-42-5) is probably combustible.
[Chemical Properties]

OFF-WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER
[Uses]

2-Amino-4-methylbenzothiazole was used in the synthesis of N-(4-methyl-1,3-benzothiazol-yl)-N-[(1,4,5,8-tetramethoxy-2-napthyl)methylidene]amine and Schiff′s base via condensation with 2-acetonaphthone.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Amino-4-methylbenzothiazole(1477-42-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-4-methylbenzothiazole(1477-42-5)MS
2-Amino-4-methylbenzothiazole(1477-42-5)1HNMR
2-Amino-4-methylbenzothiazole(1477-42-5)13CNMR
2-Amino-4-methylbenzothiazole(1477-42-5)IR1
2-Amino-4-methylbenzothiazole(1477-42-5)IR2
2-Amino-4-methylbenzothiazole(1477-42-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Amino-4-methylbenzothiazole, 98%(1477-42-5)
[Alfa Aesar]

2-Amino-4-methylbenzothiazole, 98%(1477-42-5)
[Sigma Aldrich]

1477-42-5(sigmaaldrich)
[TCI AMERICA]

2-Amino-4-methylbenzothiazole,>98.0%(T)(1477-42-5)
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