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ChemicalBook--->CAS DataBase List--->14691-89-5

14691-89-5

14691-89-5 Structure

14691-89-5 Structure
IdentificationMore
[Name]

4-ACETAMIDO-TEMPO
[CAS]

14691-89-5
[Synonyms]

2,2,6,6-TETRAMETHYL-4-ACETAMIDO-1-PIPERIDINYLOXY
2,2,6,6-TETRAMETHYL-4-ACETAMIDOPIPERIDINE-1-OXYL
4-ACETAMIDO-2,2,6,6-TEMPO
4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY
4-ACETAMIDO-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
4-ACETAMIDO-2,2,6,6-TETRAMETHYLPIPERIDINO-1-OXYL
4-ACETAMIDO-TEMPO
4-ACETAMIDO-TEMPO, FREE RADICAL
4-ACETAMINO-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY
4-ACETYLAMINO-2,2,6,6-TETRAMETHYLPIPERIDIN-1-OXYL
4-ACETYLAMINO-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL
ACETAMINO-TEMPO
1-Piperidinyloxy radical,4-(acetylamino)-2,2,6,6-tetramethyl-
1-Piperidinyloxy, 4-(acetylamino)-2,2,6,6-tetramethyl-
2,2,6,6-Tetramethyl-4-acethylamino-piperidin-1-oxyl
4-(acetylamino)-2,2,6,6-tetramethyl-1-piperidinylox
4-(acetylamino)-2,2,6,6-tetramethyl-1-Piperidinyloxy
4-Acetamido-2,2,6,6-tetramethyl-1-piperidinyloxyl
4-Acetamido-2,2,6,6-tetramethylpiperidinyloxy
N-(1-Hydroxy-2,2,6,6-tetramethyl-4-piperidinyl)acetamide
[EINECS(EC#)]

423-840-3
[Molecular Formula]

C11H21N2O2 *
[MDL Number]

MFCD00043593
[Molecular Weight]

213.3
[MOL File]

14691-89-5.mol
Chemical PropertiesBack Directory
[Appearance]

ORANGE-RED CRYSTALLINE POWDER
[Melting point ]

143-145 °C (lit.) 143-146 °C
[Boiling point ]

353.29°C (rough estimate)
[density ]

1.0451 (rough estimate)
[refractive index ]

1.4620 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Soluble in ethanol, acetone, acetonitrile, methylene chloride. Insoluble in hexane, ether.
[form ]

powder to crystaline
[color ]

Light yellow to Brown
[BRN ]

3546225
[CAS DataBase Reference]

14691-89-5(CAS DataBase Reference)
[EPA Substance Registry System]

1-Piperidinyloxy, 4-(acetylamino)-2,2,6,6-tetramethyl- (14691-89-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

1
[F ]

9
[TSCA ]

Yes
[HS Code ]

29339900
Hazard InformationBack Directory
[Chemical Properties]

ORANGE-RED CRYSTALLINE POWDER
[Uses]

4-Acetamido-TEMPO, free radical oxidizes alcohols to carbonyl compounds in the presence of TsOH.
[General Description]

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
[Purification Methods]

Dissolve the 1-oxyl in CH2Cl2, wash it with saturated K2CO3, then saturated aqueous NaCl, dry (Na2SO4), filter and evaporate. The red solid is recrystallised from aqueous MeOH, m 147.5o. [Ma & Bobbitt J Org Chem 56 6110 1991, Rozantsev & Kokhanov Bull Acad Sci USSR, Div Chem Sci 15 1422 1966, Beilstein 22/8 V 174.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-ACETAMIDO-TEMPO(14691-89-5)MS
4-ACETAMIDO-TEMPO(14691-89-5)IR1
4-ACETAMIDO-TEMPO(14691-89-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Acetylamino-2,2,6,6-tetramethylpiperidin-1-oxyl, 99%(14691-89-5)
[Alfa Aesar]

4-Acetamido-TEMPO, free radical, 98+%(14691-89-5)
[Sigma Aldrich]

14691-89-5(sigmaaldrich)
[TCI AMERICA]

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-Oxyl  Free Radical [Catalyst for Oxidation],>98.0%(GC)(14691-89-5)
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