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ChemicalBook--->CAS DataBase List--->1460-57-7

1460-57-7

1460-57-7 Structure

1460-57-7 Structure
IdentificationMore
[Name]

TRANS-1,2-CYCLOHEXANEDIOL
[CAS]

1460-57-7
[Synonyms]

TRANS-1,2-CYCLOHEX AND IOL
(+/-)-TRANS-1,2-CYCLOHEXANEDIOL
TRANS-1,2-CYCLOHEXANEDIOL
TRANS-1,2-CYCLOHEXANEDIOLE
TRANS-1,2-CYCLOHEXYLENE GLYCOL
TRANS-1,2-DIHYDROXYCYCLOHEXANE
TRANS-HEXAHYDROPYROCATECHOL
1,2-trans-Cyclohexanediol
1,2-Cyclohexanediol-trans
ca.98%
Cyclohexanediole
Hexahydrocatechol
trans-cyclohexane-1,2-diol
#ntrans-1,2-Cyclohexanediol
1,2-Cyclohexanediol, (1R,2R)-rel-
trans-hexahydrobrenzkatechin
rel-(1S*,2S*)-1,2-Cyclohexanediol
rel-(1S*,2S*)-Cyclohexane-1,2-diol
rel-1β*,2α*-Dihydroxycyclohexane
[EINECS(EC#)]

215-956-6
[Molecular Formula]

C6H12O2
[MDL Number]

MFCD00063611
[Molecular Weight]

116.16
[MOL File]

1460-57-7.mol
Chemical PropertiesBack Directory
[Appearance]

OFF-WHITE CRYSTALS OR CRYSTALLINE POWDER
[Melting point ]

101-104 °C(lit.)
[Boiling point ]

117 °C (12.7517 mmHg)
[density ]

0.9958 (rough estimate)
[vapor pressure ]

4 hPa (110 °C)
[refractive index ]

1.4270 (estimate)
[Fp ]

134 °C
[storage temp. ]

Store below +30°C.
[solubility ]

Soluble in chloroform and methanol.
[form ]

Crystals or Crystalline Powder
[pka]

14.49±0.40(Predicted)
[color ]

Off-white
[BRN ]

3193810
[CAS DataBase Reference]

1460-57-7(CAS DataBase Reference)
[NIST Chemistry Reference]

1,2-Cyclohexanediol, trans-(1460-57-7)
[EPA Substance Registry System]

1460-57-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[Autoignition Temperature]

360 °C
[HS Code ]

29061990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen peroxide-->Cyclohexene-->1-Cyclohexenyloxytrimethylsilane-->Glycidyl phenyl ether-->Methanol-->Cyclohexene oxide
[Preparation Products]

Adipaldehyde-->cis-1,2-Cyclohexanediol-->Dicyclohexano-18-crown-6-->Adipic acid-->Cyclohexane
Hazard InformationBack Directory
[Chemical Properties]

OFF-WHITE CRYSTALS OR CRYSTALLINE POWDER
[Uses]

trans-1,2-Cyclohexanediol is used as an organic chemical synthesis intermediate.
[Definition]

ChEBI: A cyclohexane-1,2-diol with trans-configuration. It is a metabolite of cyclohexene oxide and other such compounds.
[Purification Methods]

Crystallise the diol from Me2CO and dry it at 50o for several days. It can also be recrystallised from CCl4 or EtOAc and it can be distilled. The 2,4-dinitrobenzoyl derivative has m 179o. [Winstein & Buckles J Am Chem Soc 64 2780 1942.] [Beilstein 6 IV 5194.]
Spectrum DetailBack Directory
[Spectrum Detail]

TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)MS
TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)1HNMR
TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)13CNMR
TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)IR1
TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)IR2
TRANS-1,2-CYCLOHEXANEDIOL(1460-57-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

trans-1,2-Cyclohexanediol, 98%(1460-57-7)
[Alfa Aesar]

trans-1,2-Cyclohexanediol, 98%(1460-57-7)
[Sigma Aldrich]

1460-57-7(sigmaaldrich)
[TCI AMERICA]

trans-1,2-Cyclohexanediol,>99.0%(GC)(1460-57-7)
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