| Identification | More | [Name]
(R)-alpha,alpha-Diphenylmethylprolinol | [CAS]
144119-12-0 | [Synonyms]
1,1,1-DIPHENYL-(N-METHYL-PYRROLINE-2YL)-METHANOL
(2R)-1-METHYL-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINEMETHANOL
ALPHA,ALPHA-DIPHENYL-N-METHYL-D-PROLINOL
(R)-(-)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE
(R)-A,A-DIPHENYLMETHYLPROLINOL
(R)-A,A-DIPHENYL-N-METHYL-2-PYRROLIDINEMETHANOL
(R)-A,A-N-METHYL DIPHENYL-2-PYRROLIDINE METHANOL
(R)-ALPHA,ALPHA-DIPHENYLMETHYLPROLINOL
(R)-ALPHA,ALPHA-DIPHENYL-N-METHYL-2-PYRROLIDINEMETHANOL
(R)-(-)-DIPHENYL(1-METHYLPYRROLIDIN-2-YL)METHANOL
(R)-N-METHYL-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINE METHANOL
(R)-N-Methyl-alpha,alpha-diphenylpyrrolidinemethanol
a,a-Diphenyl-N-methyl-D-prolinol
(R)-Diphenyl-N-methyl-2-pyrrolidinemethanol
(r)-n-methyl-à,à-diphenylpyrrolidinemethanol
à,à-diphenyl-n-methyl-d-prolinol
α,α-diphenyl-n-methyl-d-prolinol
1,1-Diphenyl-N-methyl-D-prolinol
ALPHA,ALPHA-DIPHENYL-N-METHYL-D-PROLINOL , EE 99%
ɑ,ɑ-Diphenyl-N-methyl-D-prolinol, 97%, ee 99+% | [EINECS(EC#)]
635-081-7 | [Molecular Formula]
C18H19NO | [MDL Number]
MFCD07773068 | [Molecular Weight]
265.35 | [MOL File]
144119-12-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white to off-white crystalline powder | [Melting point ]
68-71 °C | [alpha ]
-52° (c=1, CHCl3) | [Boiling point ]
406.8±25.0 °C(Predicted) | [density ]
1.116±0.06 g/cm3(Predicted) | [refractive index ]
-55 ° (C=1, CHCl3) | [storage temp. ]
0-6°C | [form ]
Powder | [pka]
13.15±0.29(Predicted) | [color ]
white to light-yellow | [optical activity]
[α]20/D 55.0±4.0°, c = 1% in chloroform stab. with amylenes | [BRN ]
1535407 | [CAS DataBase Reference]
144119-12-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
10-34 | [HS Code ]
29339900 |
| Questions And Answer | Back Directory | [Reaction]
- Chiral amino alcohol assisted asymmetric, enantioselective, aryl transfer of triphenylboroxin to a set of aryl aldehydes in the presence of chiral amino alcohols derived from (S)-proline.
- Pyrrolidinylmethanol compound used for the zinc-catalyzed addition of arylboronic acids to aromatic aldehydes, proceeding in high yields and high enantioselectivities (up to 98% ee).
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