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ChemicalBook--->CAS DataBase List--->14024-61-4

14024-61-4

14024-61-4 Structure

14024-61-4 Structure
IdentificationBack Directory
[Name]

Bis(2,4-pentanedionato-O,O')palladium(II)
[CAS]

14024-61-4
[Synonyms]

34.7%Pd
PALLADIUM-ACETYLACETONAT
Palladous acetylacetonate
PALLADIUM ACETYLACETONATE
Palladium diacetylacetonate
PALLADIUM 2,4-PENTANEDIONATE
Palladium(Ⅱ) Acetylacetonate
PALLADIUM(II) ACETYLACETONATE
Palladium bis(acetoacetonate)
Bis(acetylaceto)palladium(II)
Palladium bis(acetylacetonate)
ACETYLACETONE PALLADIUM(II) SALT
Bis(2,4-pentanedionato)palladium
Palladium(II)acetylacetonate,99%
Bis(acetylacetonato)palladium(Ⅱ)
Palladium bis(2,4-pentanedionate)
PALLADIUM(II) 2,4-ACETYLACETONATE
PALLADIUM (II) 2,4-PENTANEDIONATE
BIS(ACETYLACETONATO)PALLADIUM(II)
PalladiuM(II) acetylacetonate,98%
PALLADIUM (II) ACETYLACETONATE 99%
Palladium, bis(2,4-pentanedionato)-
BIS(2,4-PENTANEDIONATO)PALLADIUM(II)
bis (acetylacetonate) palladium (II)
Palladium(II) acetylacetonate, 35% Pd
Bis(acetylacetonato) palladium(II) ,99%
ACETYLACETONE, PALLADIUM(II) DERIVATIVE
palladium (II) di(4-oxopent-2-en-2-oate)
PALLADIUM(II) ACETYLACETONATE FOR SYNTHE
PalladiuM(II) acetylacetonate, 35% Pd 1GR
bis(2,4-pentanedionato-o,o')palladium(ii)
4-pentanedionato-o,o’)-bis((sp-4-1)-palladiu
Bis(2,4-pentanedionato-O,O')palladium(II),99%
Palladium, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-
Palladium(II) acetylacetonate Vetec(TM) reagent grade, 98%
Bis(acetylacetonato) palladiuM(II) ,99% [C% :39.06%-39.66%]
Bis(acetylacetonato)palladiuM(Ⅱ), 35% Pd, Product of UMicore
Palladium acetylacetonate or Palladium(II)2,4-pentanedionate
Palladium(II) acetylacetonate,Palladium(II) 2,4-pentanedionate
Acetylacetone Palladium(II) Salt Palladium(II) Acetylacetonate
Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SP-4-1)-
Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd
Bis(acetylacetonato)palladium(II)~Bis(2,4-pentanedionato)palladium(II)~Palladium(II) 2,4-pentanedionate
[EINECS(EC#)]

237-859-8
[Molecular Formula]

C10H14O4Pd
[MDL Number]

MFCD00000025
[MOL File]

14024-61-4.mol
[Molecular Weight]

304.64
Chemical PropertiesBack Directory
[Appearance]

yellow orange needles
[Melting point ]

190 °C
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Store below +30°C.
[solubility ]

Soluble in benzene and chloroform.
[form ]

Solution
[color ]

Yellow to orange
[Specific Gravity]

1.862
[Water Solubility ]

INSOLUBLE
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

4136188
[InChI]

InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
[InChIKey]

RJJXYEQOOACRKP-LNKPDPKZSA-M
[SMILES]

O([Pd]O/C(/C)=C\C(=O)C)/C(/C)=C\C(=O)C
[LogP]

2.6 at 25℃
[NIST Chemistry Reference]

Bis(acetylacetonato)palladium(14024-61-4)
[EPA Substance Registry System]

Palladium, bis(2,4-pentanedionato-.kappa. O,.kappa.O')-, (SP-4-1)-(14024-61-4)
Hazard InformationBack Directory
[Chemical Properties]

yellow orange needles
[Uses]

Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.
[General Description]

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
[Flammability and Explosibility]

Highlyflammable
[Purification Methods]

It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

36-36/37/38-22
[Safety Statements ]

26-37/39
[RIDADR ]

3181
[WGK Germany ]

2
[TSCA ]

Yes
[HS Code ]

28439090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Toluene-->Acetonitrile-->Acetylacetone-->Palladium chloride-->1,3-Dichloropropane
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4)MS
Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4)IR1
Bis(2,4-pentanedionato-O,O')palladium(II)(14024-61-4)IR2
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