Identification | Back Directory | [Name]
ZIRCONIUM(IV) ACETYLACETONATE | [CAS]
17501-44-9 | [Synonyms]
ac150 X 1044 ZC 150 ZR 181 orgatixzc150 nasemuzirconium acetyl-zirconiuacetonate 2,4-pentanedione,zrderiv. ZIRCONIUM ACETYLACETONATE ZirconiuM(IV) acetylaceton Zirconium(Ⅳ) acetylacetonate ZIRCONIUM 2,4-PENTANEDIONATE ZIRCONIUM(IV) ACETYLACETONATE tetraacetylacetonatezirconium Zinconium (IV) acetylacetonate Zirconium tetraacetylacetonate ZIRCONIUM(IV) 2,4-PENTANEDIONATE ACETYLACETONE ZIRCONIUM(IV) SALT 2,4-pentanedione,zirconiumcomplex Tetrakis(acetylacetonyl)zirconium ZirconiuM(IV) acetylacetonate 98% Tetrakis(acetylacetonato)zirconium 2,4-Pentanedione, zirconium complex Zirconium tetrakis(acetylacetonate) ACETYLACETONE, ZIRCONIUM DERIVATIVE Zirconium(IV)acetylacetonate,min.98% "Zirconium 2,4-pentanedionate/ 98+%" Zirconium, tetrakis(acetylacetonato)- tetrakis(2,4-pentanedionato)-zirconiu Tetrakis(2,4-pentanedionato)zirconium TETRAKIS(ACETYLACETONATO)ZIRCONIUM(IV) Zirconium tetrakis(2,4-pentanedionate) Zirconium(IV) acetylacetonate, min. 98% ZIRCONIUM(IV) ACETYLACETONATE FOR SYNTHE Zirconium, tetrakis(pentan-2,4-dionato)- Zirconium, tetrakis(2,4-pentanedionato)- TETRAKIS(2,4-PENTANEDIONATO)ZIRCONIUM(IV) 2,4-PENTANEDIONE, ZIRCONIUM(IV) DERIVATIVE tetrakis(2,4-pentanedionato-o,o’)-zirconiu tetrakis(2,4-pentanedionato-O,o’)zirconium tetrakis(pentane-2,4-dionato-O,O')zirconium zirconium,tetrakis(2,4-pentanedionato-O,o’)- Tetrakis(acetylacetonato)-zirconium(IV)(β-form) Zirconium acetylacetonate
Acetylacetone Zirconium(IV) Salt Acetylacetone Zirconium(IV) Salt
Zirconium(IV) Acetylacetonate 4-pentanedionato-o,o’)-tetrakis((sa-8-11’’11’’1’1’’’1’1’’’)-zirconiu tetrakis(2,4-pentanedionato-kappao,kappao’)-zirconiu(sa-8-11’’11’’1’1’’’ tetrakis(2,4-pentanedionato-O,O’)-,(SA-8-11’’11’’1’1’’’1’1’’’)-Zirconium Zirconium, tetrakis(2,4-pentanedionato-O,O')-, (SA-8-11''11''1'1'''1'1''')- Zirconium, tetrakis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SA-8-11111111)- 2,4-Pentanedione zirconium(IV) derivative
Tetrakis(2,4-pentanedionato)zirconium(IV) Tetrakis(acetylacetonato)zirconium(IV)~Tetrakis(2,4-pentanedionato)zirconium(IV)~Zirconium(IV)2,4-pentanedionate 2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate | [EINECS(EC#)]
241-510-5 | [Molecular Formula]
C20H28O8Zr | [MDL Number]
MFCD00000036 | [MOL File]
17501-44-9.mol | [Molecular Weight]
487.66 |
Hazard Information | Back Directory | [Chemical Properties]
Light yellow powder | [Uses]
Zirconium(IV) 2,4-pentanedionate is used as a cross-linking agent for oxygen-containing polymers. It is used as a catalyst in organic synthesis for the nitration of o-nitrotoluene using a dinitrogen pentoxide to get 2,4-dinitrotoluenes and 2,6-dinitrotoluenes. | [Application]
Starting material for zirconium metallomesogens: zirconium tetrakis-β-diketonate liquid crystals. | [Purification Methods]
The zirconium complex crystallises from hot 95% EtOH (m 190-191o) or pet ether and sublimes in vacuo at 140o with slight decomposition. The decahydrate effloresces in air and dehydrates in a 0.1mm vacuum. Its solubility in 1L at 20o is 30g in CS2, 47g in CCl4, 44g in ethylene dibromide, 56g in acetonylacetone and 200g in *C6H6. [Young & Arch Inorg Synth II 122 1964, Beilstein 1 H 782, 1 II 835, 1 III 3121, 1 IV 3672.] |
Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
22-40-36/37/38-20/21/22-63 | [Safety Statements ]
22-24/25-36/37-26-7 | [WGK Germany ]
3
| [RTECS ]
ZH9280000
| [TSCA ]
Yes | [HS Code ]
29141900 | [Safety Profile]
Poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a cross-linking agent for oxygen-containing polymers. See also ZIRCONIUM COMPOUNDS | [Toxicity]
LD50 orally in Rabbit: 719 mg/kg |
|
|