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ChemicalBook--->CAS DataBase List--->137848-29-4

137848-29-4

137848-29-4 Structure

137848-29-4 Structure
IdentificationMore
[Name]

(S)-2'-Amino-1,1'-binaphthalen-2-ol
[CAS]

137848-29-4
[Synonyms]

R-2'-AMINO-1,1'-BINAPHTHALEN-2-OL
(R)-(+)-2-AMINO-2'-HYDROXY-1,1'-BINAPHTHYL
R-(+)-2-AMINO-2'-HYDROXY-1,1'-BINAPHTYL
(R)-(+)-NOBIN
R-NOBIN
S-2'-AMINO-1,1'-BINAPHTHALEN-2-OL
(S)-2-Amino-2'-hydroxy-1,1'-binaphthyl
S-(-)-2-AMINO-2'-HYDROXY-1,1'-BINAPHTYL
(S)-(-)-2-AMINO-2'-HYDROXY-1,2'-BINAPHTHYL
(S)-(-)-NOBIN
S-NOBIN
(S)--2-Amino-2’-hydroxy-1,1’-dinaphthalene
(S)-(-)-2-AMINO-2'-HYDROXY-1 1'-BINAPHT
S)-(-)-2-Amino-2'-Hydroxy-1,1'-Binaphthol
(S)-(+)-2-AMINO-2''-HYDROXY-1,1''-BINAPHTHYL/S-NOBIN
(S)-(-)-NOBIN 99%
S-2'-Amino-1,1'-binaphthalen-2-ol, S-NOBIN
[Molecular Formula]

C20H15NO
[MDL Number]

MFCD01882346
[Molecular Weight]

285.34
[MOL File]

137848-29-4.mol
Chemical PropertiesBack Directory
[Melting point ]

171.0 to 175.0 °C
[Boiling point ]

471.5±30.0 °C(Predicted)
[density ]

1.275
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

powder to crystal
[pka]

8.90±0.50(Predicted)
[color ]

White to Light red to Green
[CAS DataBase Reference]

137848-29-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi,N
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

3
[HS Code ]

29222990
Hazard InformationBack Directory
[Chemical Properties]

Red crystal
[Uses]

(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig?Buchwald arylation reaction.
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