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ChemicalBook--->CAS DataBase List--->13775-53-6

13775-53-6

13775-53-6 Structure

13775-53-6 Structure
IdentificationMore
[Name]

Trisodium hexafluoroaluminate
[CAS]

13775-53-6
[Synonyms]

ALUMINUM SODIUM FLUORIDE
ARTIFICAL CRYOLITE
CRYOLITE
CRYOLITE, NA3ALF6
CRYOLITE, SYNTHETIC
KRYOLITH
SODIUM ALUMINUM FLUORIDE
SODIUM FLUOROALUMINATE
SODIUM HEXAFLUOROALUMINATE
SODIUM HEXAFLUORO ALUMINUM
SYNTHETIC CRYOLITE
Trisodium hexafluoroaluminate
(oc-6-11)-aluminate(3-hexafluoro-trisodium
Aluminate(3-),hexafluoro-,trisodium,(OC-6-11)-
aluminumtrisodiumhexafluoride
hexafluoro-,trisodium,(OC-6-11)-Aluminate(3-)
hexafluoro-aluminate(3-trisodium
sodiumaluminumhexafluoride
sodiumfluoroaluminate(3-)
trisodium,(oc-6-11)-aluminate(3-hexafluoro-
[EINECS(EC#)]

237-410-6
[Molecular Formula]

AlF6Na3
[MDL Number]

MFCD00003507
[Molecular Weight]

209.94
[MOL File]

13775-53-6.mol
Chemical PropertiesBack Directory
[Appearance]

Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless
[Melting point ]

1000°C
[density ]

2.9 g/mL at 25 °C(lit.)
[refractive index ]

1.338
[solubility ]

insoluble in H2O
[form ]

Crystals
[color ]

White
[Specific Gravity]

2.9
[Water Solubility ]

Sparingly soluble in water(0.602 g/L at 20°C).
[Merck ]

14,2606
[Solubility Product Constant (Ksp)]

pKsp: 9.39
[CAS DataBase Reference]

13775-53-6(CAS DataBase Reference)
[EPA Substance Registry System]

13775-53-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R20/22:Harmful by inhalation and if swallowed .
R48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S22:Do not breathe dust .
S37:Wear suitable gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

1
[RTECS ]

BD0075000
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Sodium carbonate-->Hydrogen fluoride-->Aluminum hydroxide-->Hexafluorosilicic acid-->Calcium fluoride-->INDUSTRIAL SALT-->cryolite-->Fluoaluminic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Trisodium hexafluoroaluminate(13775-53-6).msds
Hazard InformationBack Directory
[Potential Exposure]

Sodium aluminum fluoride is used in making pesticides, ceramics, glass, and polishes; in refining reduction of aluminum, flux, glass, and enamel.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Speed in removing material from skin is of extreme importance. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water, or milk. Do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Incompatible with strong acids such as sulfuric, strong oxidizers, hydrogen fluoride.
[Chemical Properties]

Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless
[Waste Disposal]

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Sodium aluminum hexafluoride is used as a solvent (or flux) for electrolysis aluminum oxides such as bauxite, whitener for enamels and an opacifier for glass and in the industrial production of aluminum.
[Definition]

A compound found in large quantities in South Greenland. It is white or colorless, but may be reddish or brown because of impurities. Sodium hexafluoroaluminate is used as a flux in the manufacture of aluminum. It crystallizes in the monoclinic system but in forms that closely resemble cubes and isometric octahedrals.
[Flammability and Explosibility]

Nonflammable
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Sodium hexafluoroaluminate, 99.9% (metals basis)(13775-53-6)
[Sigma Aldrich]

13775-53-6(sigmaaldrich)
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