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ChemicalBook--->CAS DataBase List--->13534-97-9

13534-97-9

13534-97-9 Structure

13534-97-9 Structure
IdentificationMore
[Name]

3-Amino-6-bromopyridine
[CAS]

13534-97-9
[Synonyms]

2-AMINO-5-BROMOPYRIDINE
2-BROMO-5-AMINOPYRIDINE
3-AMINO-6-BROMOPYRIDINE
5-AMINO-2-BROMOPYRIDINE
5-BROMO-2-AMINOPYRIDINE
5-BROMOPYRIDIN-2-AMINE
5-BROMO-PYRIDIN-2-YLAMINE
6-BROMO-3-PYRIDINAMINE
6-BROMO-PYRIDIN-3-YLAMINE
AKOS BBS-00004444
LABOTEST-BB LT00129606
TIMTEC-BB SBB003823
TIMTEC-BB SBB005540
2-Bromo-5-aminoyridine
6-BROMOPYRIDIN-3-AMINE
6-Bromo-[3]pyridylamine
2-Bromo-5
5-Amino-2-bromopyridine 96%
[EINECS(EC#)]

214-019-9
[Molecular Formula]

C5H5BrN2
[MDL Number]

MFCD00006323
[Molecular Weight]

173.01
[MOL File]

13534-97-9.mol
Chemical PropertiesBack Directory
[Appearance]

Light yellow needles
[Melting point ]

75 °C
[Boiling point ]

180 °C
[density ]

1.6065 (rough estimate)
[refractive index ]

1.5182 (estimate)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

soluble in Methanol
[form ]

Powder
[pka]

1.87±0.10(Predicted)
[color ]

Beige to brown-black
[Detection Methods]

GC
[BRN ]

109102
[CAS DataBase Reference]

13534-97-9(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[F ]

10
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[PackingGroup ]

III
[HS Code ]

29333990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Iron-->Stannous chloride dihydrate-->Phosphorus tribromide-->Phosphorus oxybromide-->Aluminium-nickel-->2-Hydroxy-5-nitropyridine-->2-Bromo-5-nitropyridine-->PHOSPHORUS PENTABROMIDE-->3-Amino-2-bromopyridine-->3-Aminopyridine-->2,6-Dibromopyridin-3-amine-->2-Amino-5-nitropyridine
[Preparation Products]

6-Bromoimidazo[1,2-a]pyridine-->ethyl 4,6-dichloro-1,5-naphthyridine-3-carboxylate-->2,2'-bipyridine-5,5'-diamine-->3-Amino-6-morpholinopyridine-->2-Bromo-5-iodopyridine
Hazard InformationBack Directory
[Chemical Properties]

Light yellow needles
[Uses]

3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.
[General Description]

3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.
Spectrum DetailBack Directory
[Spectrum Detail]

5-Amino-2-bromopyridine(13534-97-9)1HNMR
5-Amino-2-bromopyridine(13534-97-9)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Amino-6-bromopyridine, 98%(13534-97-9)
[Alfa Aesar]

5-Amino-2-bromopyridine, 97%(13534-97-9)
[Sigma Aldrich]

13534-97-9(sigmaaldrich)
[TCI AMERICA]

5-Amino-2-bromopyridine,>97.0%(GC)(13534-97-9)
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