| Identification | More | [Name]
NICKEL IODIDE | [CAS]
13462-90-3 | [Synonyms]
NICKEL(II) IODIDE
NICKEL IODIDE
NICKEL IODIDE (OUS)
nickel(2+)iodide
nickeldiiodide
nickeliodide(nii2)
nickeliodide(nii2)[qr]
nickelousiodide
NICKEL(II) IODIDE, ANHYDROUS, POWDER, 99.99%
NICKEL(II) IODIDE, POWDER
Nickeliodide,anhydrous,99.5%(metalsbasis)
Nichel((Ⅱ)idide hexahydrate
Nickel(II)iodide,anhydrous(99.5%-Ni)
nickel(ii) iodide, anhydrous
nickel(ii) iodide, ultra dry
Nickel Iodide, Anhydrous
Nickel(II) iodide, anhydrous, 99.5% (metals basis)
Nickel(II) iodide, ultra dry, 99.99% (metals basis)
Diiodonickel(II)
Nickel(II) diiodide | [EINECS(EC#)]
236-666-6 | [Molecular Formula]
I2Ni | [MDL Number]
MFCD00016264 | [Molecular Weight]
312.5 | [MOL File]
13462-90-3.mol |
| Chemical Properties | Back Directory | [Appearance]
Black, crystalline powder or blue-green
crystals; hygroscopic.Soluble in alcohol and water. | [Melting point ]
797 °C(lit.)
| [Boiling point ]
sublimes [LID94] | [density ]
5.83 g/mL at 25 °C(lit.)
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
H2O: slightly soluble(lit.) | [form ]
powder
| [color ]
black | [Specific Gravity]
5.834 | [Water Solubility ]
Soluble in water and alcohols. | [Sensitive ]
Hygroscopic | [Merck ]
13,6535 | [Stability:]
hygroscopic | [CAS DataBase Reference]
13462-90-3(CAS DataBase Reference) | [EPA Substance Registry System]
Nickel iodide (NiI2) (13462-90-3) |
| Hazard Information | Back Directory | [Chemical Properties]
Black, crystalline powder or blue-green
crystals; hygroscopic.Soluble in alcohol and water. | [Uses]
Strongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.1 | [Hazard]
Toxic by ingestion. | [Preparation]
Nickel iodide can be prepared by dehydration of the hexahydrate or by the
metathetic reaction between sodium iodide and nickel(II) chloride or nitrate in ethanol.
It has the CdCl2 type lattice and is paramagnetic down to 75°K. Only one hydrate is well
characterized—the blue-green NiI2?6H20 ; unlike the other halide hexahydrates, this contains [Ni(H2O)6]2+ cations. |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R45:May cause cancer.
R61:May cause harm to the unborn child.
R42/43:May cause sensitization by inhalation and skin contact . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Hazardous Substances Data]
13462-90-3(Hazardous Substances Data) |
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