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ChemicalBook--->CAS DataBase List--->132-66-1

132-66-1

132-66-1 Structure

132-66-1 Structure
IdentificationMore
[Name]

NAPTALAM
[CAS]

132-66-1
[Synonyms]

ALANAP
ALANAP(R)
N-(1-NAPHTHYL)PHTHALAMIC ACID
NAPHTHYLPHTHALAMIC ACID
NAPTALAM
NAPTRO
N-NAPHTHALEN-1-YL-PHTHALAMIC ACID
NPA
TIMTEC-BB SBB008186
2-((1-naphthalenylamino)carbonyl)-benzoicaci
2-((1-naphthalenylamino)carbonyl)benzoicacid
6q8
acp322
alanap1
alanap10g
alanap10gat
alanap-2
alanape
alanapplus
alpha-naphthylphthalamicacid
[Molecular Formula]

C18H13NO3
[MDL Number]

MFCD00037725
[Molecular Weight]

291.3
[MOL File]

132-66-1.mol
Chemical PropertiesBack Directory
[Appearance]

solid with an unpleasant odour
[Melting point ]

185-190 °C
[Boiling point ]

433.31°C (rough estimate)
[density ]

d420 1.40
[refractive index ]

1.4800 (estimate)
[storage temp. ]

0-6°C
[solubility ]

DMF: 25 mg/ml; DMF:PBS (pH 7.2) (1:3): 0.25 mg/ml; DMSO: 15 mg/ml
[form ]

neat
[pka]

3.45±0.36(Predicted)
[color ]

White to Gray to Dark blue
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

0.2g/L(room temperature)
[Merck ]

6418
[BRN ]

2814102
[CAS DataBase Reference]

132-66-1(CAS DataBase Reference)
[EPA Substance Registry System]

Naptalam (132-66-1)
Safety DataBack Directory
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN3077 (solid); UN3082 (liquid)
[WGK Germany ]

2
[RTECS ]

TH7350000
[HS Code ]

29242990
[Hazardous Substances Data]

132-66-1(Hazardous Substances Data)
[Toxicity]

LC50 (96-hour) for bluegill sunfish 354 mg/L and rainbow trout 76 mg/L (Hartley and Kidd, 1987); acute oral LD50 of the free acid and sodium salt for rats >8,200 and 1,800 mg/kg, respectively (Ashton and Monaco, 1991).
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-1-naphthyl phthalamic acid(132-66-1).msds
Hazard InformationBack Directory
[Chemical Properties]

solid with an unpleasant odour
[Uses]

N-(1-Naphthyl)phthalamic Acid is an auxin-transport inhibitor in plants resulting in the attenuation of root growth through decreasing the cell production rate.
[Uses]

Selective preemergence herbicide used to control some grasses and many broadleaved weeds in soybeans, cucurbits, asparagus, groundnuts, potatoes and established woody ornamentals.
[Definition]

ChEBI: A dicarboxylic acid monoamide which results from addition of one equivalent of 1-naphthylamine to phthalic anhydride.
[General Description]

Naptalam is a purple crystalline solid, which can be used as an anti-geotropic agent and as an auxin (IAA) antagonist in plants.
[Agricultural Uses]

Herbicide: Used as a selective pre-emergence herbicide to control broadleaf weeds and grasses in soybeans, cucumbers, melons, peanuts and woody ornamentals. Not currently registered for use in the U.S. or EU countries. There are 25 global suppliers.
[Trade name]

N-1-naphthyl- Trade Names: ALANAP®[C]; ALANAPE®; ANCRACK®; DYANAP®; GRELUTIN®; MORCRAN ®; NAPTRO®; NIP-A-THIN®; PEACH-THIN®; RESCUE®[C]; 6Q8®; SOLO®
[Environmental Fate]

Soil/Plant. Degrades in soils and plants forming 1-naphthylamine and phthalic acid (Hartley and Kidd, 1987; Humburg et al., 1989). Residual activity in soil is limited to approximately 3 to 4 months (Hartley and Kidd, 1987).
Chemical/Physical. Forms N-(1-naphthyl)phthalimide at elevated temperatures (Worthing and Hance, 1991). Naptalam will precipitate as the free acid in very acidic waters or in extremely hard waters (Humburg et al., 1989).
[Purification Methods]

Crystallise the herbicide from EtOH (m 183-185o). The Na salt has m 185o. [Beilstein 12 H 1236, 12 I 525, 12 III 2876.]
Spectrum DetailBack Directory
[Spectrum Detail]

NAPTALAM(132-66-1)1HNMR
NAPTALAM(132-66-1)13CNMR
NAPTALAM(132-66-1)IR1
NAPTALAM(132-66-1)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

132-66-1(sigmaaldrich)
[TCI AMERICA]

N-(1-Naphthyl)phthalamic Acid,>99.0%(T)(132-66-1)
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