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ChemicalBook--->CAS DataBase List--->1234-35-1

1234-35-1

1234-35-1 Structure

1234-35-1 Structure
IdentificationMore
[Name]

Nalpha-Cbz-L-Arginine
[CAS]

1234-35-1
[Synonyms]

CBZ-ARG-OH
CBZ-L-ARGININE
CBZ-L-ARG-OH
L-ARGININE, N2-[(PHENYLMETHOXY)CARBONYL]-
N2-CARBOBENZYLOXY-L-ARGININE
N-ALPHA-BENZYLOXYCARBONYL-L-ARGININE
NALPHA-CARBOBENZOXY-L-ARGININE
N-ALPHA-CARBOBENZYLOXY-L-ARGININE
NALPHA-CBZ-L-ARGININE
N-ALPHA-Z-L-ARGININE
N-BENZYLOXYCARBONYL-L-ARGININE
N-CARBOBENZOXY-L-ARGININE
N-CBZ-L-ARGININE-OH
Z-ARGININE
Z-ARG-OH
Z-L-ARGININE
Z-L-ARG-OH
n2-[(phenylmethoxy)carbonyl]-l-arginin
Nα-Z-L-Arginine
N2-Carbobenzyloxy-L-arginine
[EINECS(EC#)]

214-973-6
[Molecular Formula]

C14H20N4O4
[MDL Number]

MFCD00001762
[Molecular Weight]

308.33
[MOL File]

1234-35-1.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

171-174 °C (dec.)(lit.)
[alpha ]

-11 º (c=0.5, 0.5N HCl 24 ºC)
[Boiling point ]

448.73°C (rough estimate)
[density ]

1.1765 (rough estimate)
[refractive index ]

-10 ° (C=5.5, 0.2mol/L HCl)
[storage temp. ]

2-8°C
[solubility ]

DMSO, Water
[form ]

Solid
[pka]

3.90±0.21(Predicted)
[color ]

White
[optical activity]

[α]20/D 9±1°, c = 5% in 1 M HCl
[BRN ]

2169267
[CAS DataBase Reference]

1234-35-1(CAS DataBase Reference)
[EPA Substance Registry System]

1234-35-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29252900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

N(alpha)-carbobenzoxyarginine-4-nitroanilide-->Z-ARG(NO2)-OH-->Z-ORN-OH-->H-PHE-NH2-->L(+)-Arginine-->Cyanamide-->Benzyl chloroformate-->Benzyl alcohol-->4-Nitroaniline
[Preparation Products]

N-Phospho-L-arginine-->PHOSPHO-L-ARGININE SODIUM-->Z-ARG(Z)2-OH-->4-Nitrophenol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Nalpha-Cbz-L-Arginine(1234-35-1).msds
Hazard InformationBack Directory
[Chemical Properties]

white powder
[Uses]

Z-L-Arginine is used in the synthesis of renin inhibitors containing phosphorous acid derivatives at the scissile bond. Also used in the synthesis of a peptide deformylase inhibitor BB-3497.
[reaction suitability]

reaction type: solution phase peptide synthesis
Spectrum DetailBack Directory
[Spectrum Detail]

Nalpha-Cbz-L-Arginine(1234-35-1)MS
Nalpha-Cbz-L-Arginine(1234-35-1)1HNMR
Nalpha-Cbz-L-Arginine(1234-35-1)13CNMR
Nalpha-Cbz-L-Arginine(1234-35-1)IR1
Nalpha-Cbz-L-Arginine(1234-35-1)IR2
Nalpha-Cbz-L-Arginine(1234-35-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

N(alpha)-Benzyloxycarbonyl-L-arginine, 99%(1234-35-1)
[Sigma Aldrich]

1234-35-1(sigmaaldrich)
[TCI AMERICA]

Nalpha-Carbobenzoxy-L-arginine,>97.0%(T)(1234-35-1)
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