| Identification | More | [Name]
Azodicarbonamide | [CAS]
123-77-3 | [Synonyms]
1,1'-AZOBISFORMAMIDE
1,1-AZOBISFORMAMIDE
Azobisformamide
Azodicarbamide
AZODICARBONAMIDE
AZODICARBOXAMIDE
AZODICARBOXYLIC ACID DIAMIDE
AZOFOAM E
DICARBAMOYLDIMIDE
1,1’-azobiscarbamide
1,1’-azobis-formamid
1,1’-azodiformamide
1,1'-Azodiformamide
abfa
az
azobiscarbonamide
azobiscarboxamide
azodicarboamide
Azodiformamide
celogenaz | [EINECS(EC#)]
204-650-8 | [Molecular Formula]
C2H4N4O2 | [MDL Number]
MFCD00007958 | [Molecular Weight]
116.08 | [MOL File]
123-77-3.mol |
| Chemical Properties | Back Directory | [Appearance]
orange crystalline powder | [Melting point ]
220-225 °C (dec.)(lit.)
| [Boiling point ]
217.08°C (rough estimate) | [density ]
1.65 | [vapor pressure ]
0Pa at 25℃ | [refractive index ]
1.4164 (estimate) | [Fp ]
225 °C | [storage temp. ]
Flammables area | [solubility ]
water: soluble0.033g/L at 20°C | [form ]
Solid | [pka]
14.45±0.50(Predicted) | [color ]
Yellow to orange-red crystalline powder | [Odor]
odorless | [PH]
7 ( in H2O, neutral) | [Stability:]
Highly flammable. Incompatible with strong oxidizing agents, strong acids, strong bases, heavy metal salts. | [Water Solubility ]
SOLUBLE IN HOT WATER | [Merck ]
14,919 | [BRN ]
1758709 | [InChIKey]
XOZUGNYVDXMRKW-AATRIKPKSA-N | [LogP]
-1.148 (est) | [Uses]
Azodicarbonamide is a dough conditioner that exists as a yellow to
orange-red crystalline powder practically insoluble in water. it is
used in aging and bleaching cereal flour to produce a more manage-
able dough and a lighter, more voluminous loaf of bread. it is used
in bread flours and bread as a dough conditioner. it can be used with
the oxidizing agent potassium bromate. a typical use level is less
than 45 ppm. | [CAS DataBase Reference]
123-77-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Diazenedicarboxamide(123-77-3) | [EPA Substance Registry System]
123-77-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R42:May cause sensitization by inhalation.
R44:Risk of explosion if heated under confinement. | [Safety Statements ]
S22:Do not breathe dust .
S24:Avoid contact with skin .
S37:Wear suitable gloves . | [RIDADR ]
UN 3242 4.1/PG 2
| [WGK Germany ]
1
| [RTECS ]
LQ1040000
| [HazardClass ]
4.1 | [PackingGroup ]
II | [HS Code ]
29270000 | [Safety Profile]
Flammable solid. When
heated to decomposition it emits toxic
fumes of NOx. | [Hazardous Substances Data]
123-77-3(Hazardous Substances Data) | [Toxicity]
LD50 oral in rat: > 6400mg/kg |
| Hazard Information | Back Directory | [General Description]
A yellow to orange powder. Insoluble in water and common solvents. Soluble in dimethyl sulfoxide. Nontoxic. | [Reactivity Profile]
AZODICARBONAMIDE(123-77-3) is easily ignited and burns rapidly. Confined samples show a high rate of pressure rise during thermal decomposition, which produces carbon monoxide and nitrogen. Sensitive to temperatures exceeding 122°F. May be sensitive to exposure to light. Stable in bulk when stored for two weeks at temperatures up to 140°F. Slightly unstable in water suspension (showed1.3% decomposition at 2 mg/mL over a two-week period at room temperature in the light but no decomposition at 41°F over a two-week period in the dark . Reacts with hot water to give nitrogen, carbon monoxide, and ammonia [Hawley]. Decomposes in hot hydrochloric acid. Incompatible with strong acids and bases, and with compounds of metals. | [Air & Water Reactions]
Highly flammable. Water insoluble. Dust may form an explosive mixture in air. | [Health Hazard]
Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce irritating, toxic and/or corrosive gases. Runoff from fire control may cause pollution. | [Fire Hazard]
Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames. Some may decompose explosively when heated or involved in a fire. May burn violently. Decomposition may be self-accelerating and produce large amounts of gases. Vapors or dust may form explosive mixtures with air. | [Chemical Properties]
orange crystalline powder | [Definition]
ChEBI: Azodicarbonamide is an organic molecular entity. | [Flammability and Explosibility]
Nonflammable |
| Questions And Answer | Back Directory | [Description]
Azodicarbonamide is a synthetic chemical that exists at ambient temperature as a yellow-orange crystalline solid. Azodicarbonamide is mainly used as a blowing agent in the rubber and plastics industries in the expansion of a wide range of polymers, including polyvinyl chloride, polyolefins, and natural/synthetic rubbers. Azodicarbonamide is also used as a food additive, such as an aging and bleaching ingredient in cereal flour and as a dough conditioner in bread baking.
| [References]
[1] https://www.fda.gov
[2] http://www.who.int
[3] C. D. Han, Y. W. Kim and K. D. Malhotra, A study of foam extrusion using a chemical blowing agent , Journal of Applied Polymer Science, 1976, vol. 20, 1583-1595
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