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ChemicalBook--->CAS DataBase List--->112-86-7

112-86-7

112-86-7 Structure

112-86-7 Structure
IdentificationMore
[Name]

cis-13-Docosenoic acid
[CAS]

112-86-7
[Synonyms]

13C DOCOSENOIC ACID
13-DOCOSENOIC ACID
13(Z)-DOCOSENOIC ACID
CIS-13-DOCOSENOIC ACID
DELTA 13 CIS DOCOSENOIC ACID
DOCOSENOIC ACID
ERUCIC ACID
ERUCIC ACID (C22:1,[CIS]-13)
(Z)-13-DOCOSENOIC ACID
(13Z)-13-Docosenoic acid
(z)-13-docosenoicaci
(Z)-docos-13-enoicacid
13-cis-Docosenoicacid
13-Docosenoic acid, (Z)-
13-Docosenoicacid,(13Z)-
13-Docosenoicacid,(Z)-
13-Docosensαure
cis-13-docosenecarboxylicacid
cis-13-Docosensαure
cis-docos-13-enoicacid
[EINECS(EC#)]

204-011-3
[Molecular Formula]

C22H42O2
[MDL Number]

MFCD00063188
[Molecular Weight]

338.57
[MOL File]

112-86-7.mol
Chemical PropertiesBack Directory
[Melting point ]

28-32 °C (lit.)
[Boiling point ]

358 °C/400 mmHg (lit.)
[density ]

0,86 g/cm3
[refractive index ]

nD45 1.4534; nD65 1.44794
[Fp ]

265°C/15mm
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

4.78±0.10(Predicted)
[color ]

White to Off-White
[Merck ]

14,3674
[BRN ]

1728049
[LogP]

9.459 (est)
[CAS DataBase Reference]

112-86-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Erucic acid(112-86-7)
[EPA Substance Registry System]

112-86-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

1
[RTECS ]

JR1280000
[F ]

10-23
[TSCA ]

Yes
[HS Code ]

29161900
[Hazardous Substances Data]

112-86-7(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

RAPESEED OIL-->FATTY ACID MIXTURE
[Preparation Products]

Erucamide-->1,11-Undecanedicarboxylic acid-->CANOLA OIL-->RAPESEEDOIL,SUPERGLYCERINATED,FULLYHYDROGENATED-->Rape oil, hydrogenated-->Cyclopentadecanone, 2-hydroxy-->CIS-13-DOCOSENOL-->13-bromotridecanoic acid-->ERUCIC ACID METHYL ESTER
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

cis-13-Docosenoic acid(112-86-7).msds
Hazard InformationBack Directory
[Description]

Erucic acid also known as cis-13-Docosenoic acid is a monounsaturated omega-9 fatty acid. It occurs at high concentrations mainly in the seeds of species of the Brassicaceae (e.g. rape seed or mustard seed, and seeds from vegetable crops such as kales, cabbages and turnips).
High-erucic acid oils are used either directly as lubricants (e.g. in the manufacture of rubber additives) or in formulations. They are used as spinning lubricants in the textile, steel, and shipping industries; as cutting, metal-forming, rolling, fabricating, and drilling oils; and as marine lubes. Erucic acid can also be oxidatively cleaved to brassylic acid for use in the production of polyesters. The oxidative cleavage of erucic acid can be performed via ozonolysis or by reaction with hydrogen peroxide in the presence of an inorganic oxide catalyst. Erucic acid can be used to prepare useful nitrogen derivatives: behenyl amine is used in a corrosion inhibitor; disubstituted amides are effective plasticizers and erucamide is an excellent slip and antiblocking agent for plastic films.
[Chemical Properties]

White crystalline
[Uses]

13(Z)-Docosenoic acid is a 22-carbon monounsaturated fatty acid. It is found predominantly in canola oil. 13(Z)-Docosenoic acid is metabolized to oleic acid in vivo. Diets rich in 13(Z)-docosenoic acid were shown to cause heart lipidosis in experimental animals. The C-1 amide of docosenoic acid has been identified as one of the anandamide-related neurotransmitters associated with sleep.
[Uses]

Erucic acid has many of the same uses as mineral oils, but it is more readily biodegradable than some. It has limited ability to polymerize and dry for use in oil paints. Like other fatty acids, it can be converted into surfactants or lubricants, and can be used as a precursor to bio-diesel fuel.
Derivatives of erucic acid have many further uses, such as behenyl alcohol ( CH3(CH2)21OH ) , a pour point depressant (enabling liquids to flow at a lower temperature), and silver behenate, for use in photography. It is also used as an ingredient in appetite suppressants.
[Uses]

Erucic acid is a long-chain alcohol that acts as an inhibitor of fatty acid oxidation in the heart. Erucic acid originates in rapeseed plants, and is the major fatty acid constituent of rapeseed plant oil extracts and canola oil.
[Definition]

ChEBI: A docosenoic acid having a cis- double bond at C-13. It is found particularly in brassicas - it is a major component of mustard and rapeseed oils and is produced by broccoli, Brussels sprouts, kale, and wallflowers.
[Biotechnological Applications]

Erucic acid is produced by elongation of oleic acid via oleoylcoenzyme A and malonyl- CoA. Erucic acid is broken down into shorter- chain fatty acids in the human liver by the long - chain Acyl CoA dehydrogenase enzyme.
[storage]

Store at -20°C
[Purification Methods]

Crystallise erucic acid from MeOH. [Beilstein 2 IV 1676.]
[References]

[1] J.M. Vargas-Lopez, D. Wiesenborna, K. Tostenson , L. Cihacek (1999) Processing of Crambe for Oil and Isolation of Erucic Acid, JAOCS, 76, 801-809 DOI:10.1007/S11746-999-0069-4
[2] H. J. Nieschlag, I. A. Wolff (1971) Industrial uses of high erucic oils, JAOCS, 48, 723-727 DOI:10.1007/BF02638529
[3] Erucic Acid (22:1n-9) in Fish Feed, Farmed, and Wild Fish and Seafood Products DOI:10.3390/nu10101443
[4] Erucic acid--an inhibitor of fatty acid oxidation in the heart. DOI:10.1016/0005-2760(72)90130-0
[5] Purification-of-Laboratory-Chemicals
[6] Christophersen, B. & Bremer, J.: BBA-Lipid. Lipid Met., 280, 506 (1972); Ecke, W., et al.: Theor. Appl. Gen., 91, 972 (1995); Metz, J., et al.: Plant Phys., 122, 635 (2000)
Spectrum DetailBack Directory
[Spectrum Detail]

Erucic Acid(112-86-7)MS
Erucic Acid(112-86-7)1HNMR
Erucic Acid(112-86-7)IR1
Erucic Acid(112-86-7)IR2
Erucic Acid(112-86-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Erucic acid, tech. 90%(112-86-7)
[Sigma Aldrich]

112-86-7(sigmaaldrich)
[TCI AMERICA]

Erucic Acid,>85.0%(GC)(112-86-7)
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