Identification | More | [Name]
3-BROMOCHLOROBENZENE | [CAS]
108-37-2 | [Synonyms]
1-BROMO-3-CHLOROBENZENE 3-BROMOCHLOROBENZENE M-BROMOCHLOROBENZENE M-CHLOROBROMOBENZENE 1-bromo-3-chloro-benzen 1-Chloro-3-bromobenzene 3-Bromo-1-chlorobenzene 3-Chlorobromobenzene 3-Chlorophenyl bromide 3-chlorophenylbromide Benzene, 1-bromo-3-chloro- benzene,1-bromo-3-chloro- m-Bromophenyl chloride m-bromophenylchloride m-Chlorophenyl bromide m-chlorophenylbromide 3-BROMOCHLOROBENZENE 99% 3-Bromochlorobenzene/1-Bromo-3-chlorobenzene Bromochlorobenzene, m- | [EINECS(EC#)]
203-575-8 | [Molecular Formula]
C6H4BrCl | [MDL Number]
MFCD00000568 | [Molecular Weight]
191.45 | [MOL File]
108-37-2.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
CY9005000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29039990 |
Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Uses]
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031 | [General Description]
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. |
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