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ChemicalBook--->CAS DataBase List--->107-81-3

107-81-3

107-81-3 Structure

107-81-3 Structure
IdentificationMore
[Name]

2-Bromopentane
[CAS]

107-81-3
[Synonyms]

1-METHYLBUTYL BROMIDE
(+/-)-2-BROMOPENTANE
2-BROMOPENTANE
(+/-)-2-PENTYL BROMIDE
2-PENTYL BROMIDE
SEC-AMYL BROMIDE
2-bromo-pentan
2-Pentylbromid
pentane,2-bromo-
sec-Pentylbromide
2-Bromopentane, tech., 90%
2-BROMOPENTANE MIN 955
2-Bromopentane (contains ca. 12% 3-Bromopentane)
(±)-2-Bromopentane, (±)-2-Pentyl bromide
2-Bromopentane, 90%,tech
[EINECS(EC#)]

203-521-3
[Molecular Formula]

C5H11Br
[MDL Number]

MFCD00000160
[Molecular Weight]

151.04
[MOL File]

107-81-3.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

-95.5 °C
[Boiling point ]

116-117 °C(lit.)
[density ]

1.223 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.441(lit.)
[Fp ]

69 °F
[storage temp. ]

Flammables area
[form ]

Liquid
[color ]

Clear
[Stability:]

Stable. Highly flammable. Incompatible with strong bases, strong oxidizing agents.
[Water Solubility ]

practically insoluble
[BRN ]

1718829
[InChIKey]

LGAJYTCRJPCZRJ-UHFFFAOYSA-N
[CAS DataBase Reference]

107-81-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Pentane, 2-bromo-(107-81-3)
[EPA Substance Registry System]

107-81-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 2343 3/PG 2
[WGK Germany ]

3
[RTECS ]

RZ9800000
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29033990
[Safety Profile]

Poison by intraperitoneal route. Mildly toxic by inhalation. A local irritant and narcotic in high concentration. Ingestion can cause liver damage. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Pentane, 3,3-dibromo--->methyl 1-methylbutyl ether-->p-Toluenesulfonic acid 1-methylbutyl ester-->Methylcyclobutane.-->TRANS-2-PENTENE-->(S)-(+)-2-Pentanol-->3-Bromopentane-->1,4-Dibromopentane-->2-Pentanol
[Preparation Products]

5-(sec-pentyl)barbituric acid-->(+/-)-THIOPENTAL-->5-METHYL-2-OCTANONE-->4-METHYLTETRADECANE-->sec-Pentylbromomagnesium
Hazard InformationBack Directory
[General Description]

A colorless to yellow-colored liquid with a strong odor. Flash point 90°F. Slightly denser than water and insoluble in water. Vapors heavier than air. May irritate skin and eyes. In high concentrations the vapors may be narcotic.
[Reactivity Profile]

2-BROMOPENTANE(107-81-3) is incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Health Hazard]

Irritating to eyes, nose, throat, and upper respiratory tract. Causes skin irritation.
[Chemical Properties]

2-bromopentane is a colorless to yellow-colored liquid with a strong odor. It is an optically active compound because it contains an asymmetric carbon (chiral carbon). An asymmetric carbon is carbon atom that is attached to four different types of atoms or groups of atoms. In 2-Bromopentance, the central carbon atom is attached to four different types of atoms (CH2, CH3, Br, H), hence it is an optically active compound.
[Uses]

Used as a chemical intermediate.
[Purification Methods]

Dry it over K2CO3 and distil it through a short Vigreux column (p 11). [IR: Pines et al. J Am Chem Soc 74 4063 1952, Brown & Wheeler J Am Chem Soc 78 2199 1956, Beilstein 1 IV 312.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Bromopentane (107-81-3).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2-Bromopentane(107-81-3)1HNMR
2-Bromopentane(107-81-3)IR1
2-Bromopentane(107-81-3)IR2
2-Bromopentane(107-81-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Bromopentane, tech., 90%(107-81-3)
[Alfa Aesar]

2-Bromopentane, tech. 90%(107-81-3)
[Sigma Aldrich]

107-81-3(sigmaaldrich)
[TCI AMERICA]

2-Bromopentane  (contains ca. 12% 3-Bromopentane),>85.0%(GC)(107-81-3)
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