| Identification | More | [Name]
ALLYLTRICHLOROSILANE | [CAS]
107-37-9 | [Synonyms]
3-TRICHLOROSILYLPROPENE
ALLYLTRICHLOROSILANE
TRICHLOROALLYLSILANE
Allyl trichlorosilane, stabilized
allylsilicone
allylsiliconetrichloride
allyltrichloro-silan
allyltrichlorosilane,stabilized
Propen-3-yltrichlorosilane
Silane, allyltrichloro-
Silane, trichloroallyl-
trichloro-2-propenyl-silan
trichloro-2-propenyl-silane
trichloroallyl-silan | [EINECS(EC#)]
203-485-9 | [Molecular Formula]
C3H5Cl3Si | [MDL Number]
MFCD00000486 | [Molecular Weight]
175.52 | [MOL File]
107-37-9.mol |
| Chemical Properties | Back Directory | [Appearance]
Allyl trichhlorosilane is a volatile, corrosive, flammable, colorless liquid. Irritating odor. | [Melting point ]
35℃ | [Boiling point ]
116 °C750 mm Hg(lit.) | [density ]
1.211 g/mL at 25 °C(lit.)
| [vapor density ]
>1 (vs air)
| [vapor pressure ]
10 mm Hg ( 16.1 °C)
| [refractive index ]
n20/D 1.443(lit.)
| [Fp ]
88 °F
| [storage temp. ]
Flammables area | [solubility ]
soluble in MeCN, THF, CH2Cl2, toluene, benzene,
etc.; not compatible with protic solvents, acetone, and other
ketones. Dipolar aprotic solvents (DMF, DMSO, HMPA, etc.)
coordinate Si, thereby increasing the reactivity of C3H5SiCl3
with electrophiles. | [form ]
Liquid | [color ]
Clear colorless to slightly yellow | [Specific Gravity]
1.211 | [Water Solubility ]
Soluble in THF, toluene, benzene. Reacts with water. | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [BRN ]
1743449 | [CAS DataBase Reference]
107-37-9(CAS DataBase Reference) | [EPA Substance Registry System]
Silane, trichloro-2-propen-1-yl- (107-37-9) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1724 8/PG 2
| [WGK Germany ]
1
| [RTECS ]
VV1530000
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29319090 | [Safety Profile]
Poison by intravenous route. Corrosive. See ALLYL COMPOUNDS. When heated to decomposition it emits toxic Cl-. A dangerous fire hazard. To fight fire, use foam, mist, spray, dry chemical. | [Hazardous Substances Data]
107-37-9(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with a pungent odor. Flash point of 95°F. Corrosive to metals and tissue. | [Reactivity Profile]
Chlorosilanes, such as ALLYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. | [Health Hazard]
Inhalation of vapor irritates mucous membranes. Liquid causes severe burns of eyes and skin and severe internal burns if ingested. | [Potential Exposure]
Used to make silicones and glass fiber finishes. | [First aid]
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
| [Shipping]
UN1724 Allyltrichlorosilane, stabilized, Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid | [Incompatibilities]
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Chlorosilanes react vigorously with bases and both organic and inorganic acids generating toxic and/or flammable gases. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride gas. They may also produce flammable gaseous hydrogen. Attacks metals in the presence of moisture. Avoid all sources of ignition. | [Chemical Properties]
Allyl trichhlorosilane is a volatile, corrosive, flammable, colorless liquid. Irritating odor. | [Chemical Properties]
Clear colorless to slightly yellow liquid | [Physical properties]
bp 116°C/750 Torr; nD 1.4450; d 1.211. | [Uses]
Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes. | [Uses]
Intermediate for silicones, fiberous glass finishes. | [Preparation]
allyl trichlorosilane is conveniently prepared
from allyl chloride, Cl3SiH, CuCl, and (i-Pr)2EtN
(or Et3N) in ether at 20°C,or from allyl chloride and coppersilicon
powder at 250°C.Other methods include the reaction
of allyl chloride with SiCl4 in the presence of CuCl and Et3N7 or in the presence of Cp2Ni and HMPA at 90°C,the flash
pyrolysis of allyl chloride with Si2Cl2 in PhCl at 500°C,the
reaction of allylMgBr with SiCl4,coupling of allene with
Cl3SiH, catalyzed by (Ph3P)4Pd (120°C, 5 h),11 and the elimination
of HCl from Cl(CH2)3SiCl3 using, e.g., quinoline as
base.The analogous (E)-crotyl trichlorosilane can be synthesized
from (E)-crotyl chloride, Cl3SiH, CuCl, and (i-Pr)2EtN in
ether at 20°C,or from (E)-crotyl chloride, SiCl4, and
Cp2Ni in HMPA at 90°C.The reaction of (E)-crotyl chloride
with Cl3SiH and Bu4PCl at 150°C has also been reported.
(Z)-crotyl trichlorosilane, on the other hand, was prepared via
the 1,4-addition of Cl3SiH to butadiene, catalyzed by (Ph4P)4Pd
(at 20°Cor?78°C)or by (PhCN)2PdCl2;this hydrosilylation
can also be catalyzed by Nior proceed uncatalyzed
at 500–600°C.Analogous trifluoro and tribromo derivatives
C3H5SiX3 (X = F and Br) have also been described. |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|