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ChemicalBook--->CAS DataBase List--->106-35-4

106-35-4

106-35-4 Structure

106-35-4 Structure
IdentificationMore
[Name]

3-Heptanone
[CAS]

106-35-4
[Synonyms]

3-HEPTANONE
BUTYL ETHYL KETONE
ETHYL BUTYL KETONE
ETHYL N-BUTYL KETONE
FEMA 2545
HEPTAN-3-ONE
HEPTANONE, 3-
N-BUTYL ETHYL KETONE
3-Heptanon
3-Oxoheptane
Aethylbutylketon
Eptan-3-one
Ethylbutylcetone
ethylbutylcetone(french)
Ethylbutylketon
Ethyl-butylketon
Etilbutilchetone
heptan-3-
Heptan-3-on
heptan-3-on(dutch,german)
[EINECS(EC#)]

203-388-1
[Molecular Formula]

C7H14O
[MDL Number]

MFCD00009483
[Molecular Weight]

114.19
[MOL File]

106-35-4.mol
Chemical PropertiesBack Directory
[Appearance]

Ethyl butyl ketone is a colorless liquid with a powerful, fruity odor.
[Melting point ]

-39 °C (lit.)
[Boiling point ]

146-149 °C (lit.)
[density ]

0.818 g/mL at 25 °C(lit.)
[vapor pressure ]

1.4 at 25 °C (quoted, Verschueren, 1983)
[FEMA ]

2545
[refractive index ]

n20/D 1.408(lit.)
[Fp ]

106 °F
[storage temp. ]

Flammables area
[solubility ]

4.3g/l
[form ]

Liquid
[color ]

Clear slightly yellow
[Odor]

at 1.00 % in dipropylene glycol. powerful green fatty fruity
[Stability:]

Stable. Flammable. Incompatible with strong oxidizing agents, strong bases, strong reducing agents. May form peroxides in storage if in contact with air-store under inert gas.
[Odor Type]

green
[Water Solubility ]

3.3 g/L (20 ºC)
[JECFA Number]

285
[BRN ]

506161
[Henry's Law Constant]

4.38 x 10-4(atm?m3/mol) at 37 °C (static headspace-GC, Bylaite et al., 2004)
[Dielectric constant]

12.9(22℃)
[Exposure limits]

TLV-TWA 230 mg/m3 (50 ppm) (ACGIH); IDLH 3000 ppm (NIOSH). .
[LogP]

1.97
[Uses]

Solvent mix for air-dried and baked finishes, for polyvinyl and nitrocellulose resins.
[CAS DataBase Reference]

106-35-4(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Heptanone(106-35-4)
[EPA Substance Registry System]

106-35-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R38:Irritating to the skin.
R40:Limited evidence of a carcinogenic effect.
R48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R36:Irritating to the eyes.
R20:Harmful by inhalation.
R10:Flammable.
[Safety Statements ]

S36:Wear suitable protective clothing .
S24:Avoid contact with skin .
[OEB]

A
[OEL]

TWA: 50 ppm (230 mg/m3)
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

2
[RTECS ]

MJ5250000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29141990
[Safety Profile]

Moderately toxic by ingestion and inhalation. A skin and eye irritant. A flammable liquid. Can react with oxidizing materials. To fight fire, use foam, Co2, dry chemical. See also KETONES.
[Hazardous Substances Data]

106-35-4(Hazardous Substances Data)
[Toxicity]

Acute oral LD50 for rats 2,760 mg/kg (quoted, RTECS, 1985).
[IDLA]

1,000 ppm
Hazard InformationBack Directory
[General Description]

Colorless odorless liquid with a mild fruity odor. Flash point 140°F.
[Reactivity Profile]

ETHYL BUTYL KETONE(106-35-4) is reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion. Reacts with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. May react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4. Irritating vapors and toxic gases may be formed when involved in fire [USCG, 1999].
[Air & Water Reactions]

Flammable.
[Hazard]

Moderate fire risk.
[Health Hazard]

Short term exposure can cause irritation of eyes, nose, throat and lungs. High concentrations may cause headache, dizziness or unconsciousness.
[Potential Exposure]

Ethyl butyl ketone is used as a solvent and as an intermediate in organic synthesis. It is a solvent for vinyl and nitrocellulose resins. It is used in food flavoring
[Fire Hazard]

Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1224 Ketones, liquid, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
[Incompatibilities]

May form explosive mixture with air. Violent reaction with strong oxidizers, acetaldehyde, perchloric acid. Attacks some plastics, rubber and coatings
[Description]

3-Heptanone has a powerful, green, fatty, fruity odor and a melon, banana flavor. Prepared from n-hept-2-one by hydration.
[Chemical Properties]

3-Heptanone has a fruity, green, fatty, sweet, ethereal, powerful odor and a melon, banana favor.
[Chemical Properties]

colourless liquid
[Chemical Properties]

Ethyl butyl ketone is a colorless liquid with a powerful, fruity odor.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed
[Occurrence]

Reported found in apple juice, banana, peach, pear, spearmint oil, Parmesan cheese, butter, cream, lean fsh, fsh oil, roasted chicken, cooked beef, coffee, peanut oil, pecan, yellow passion fruit, plumcot, beans, plum brandy, sesame seed, mango and cooked shrimps
[Definition]

ChEBI: A dialkyl ketone with butyl and ethyl as the two alkyl groups.
[Preparation]

From n-hept-2-one by hydration.
[Production Methods]

EnBK is produced either by catalytic dehydrogenation of 3-heptanol or by hydrogenation of the mixed alcohol condensation product of propionaldehyde and methyl ethyl ketone. Commercial samples can be 95% pure.
[Aroma threshold values]

Detection: 7 5 to 160 ppb.
[Taste threshold values]

Taste characteristics at 50 ppm: ketonic, with a cheese-like creamy character.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 94, p. 1788, 1972 DOI: 10.1021/ja00760a084
Tetrahedron Letters, 23, p. 2379, 1982 DOI: 10.1016/S0040-4039(00)87347-5
Synthetic Communications, 22, p. 1589, 1992 DOI: 10.1080/00397919208021632
[Environmental Fate]

Chemical/Physical. 3-Heptanone will not hydrolyze because it has no hydrolyzable functional group.
[Solubility in organics]

Insoluble in water, soluble in alcohol, miscible with oils.
[storage]

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trained onits proper handling and storage. Ethyl butyl ketone must bestored to avoid contact with oxidizers, such as peroxides,chlorates, perchlorates, permanganates, and nitrates, becauseviolent reactions occur. Store in tightly closed containers ina cool, well-ventilated area away from heat. Sources of ignition, such as smoking and open flames, are prohibited whereethyl butyl ketone is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Heptanone(106-35-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3-Heptanone(106-35-4)MS
3-Heptanone(106-35-4)1HNMR
3-Heptanone(106-35-4)13CNMR
3-Heptanone(106-35-4)IR1
3-Heptanone(106-35-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Heptanone, 98%(106-35-4)
[Alfa Aesar]

3-Heptanone, 98%(106-35-4)
[Sigma Aldrich]

106-35-4(sigmaaldrich)
[TCI AMERICA]

3-Heptanone,>98.0%(GC)(106-35-4)
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