Identification | More | [Name]
12-HYDROXYSTEARIC ACID | [CAS]
106-14-9 | [Synonyms]
(+/-)-12-HYDROXYOCTADECANOIC ACID 12-HYDROXYOCTADECANOIC ACID 12-HYDROXYSTEARIC ACID DL-12-HYDROXYOCTADECANOIC ACID DL-12-HYDROXYSTEARIC ACID LEMOSOL COAGULANT 12-hydroxy-octadecanoicaci 12-hydroxystearic 12-hydroxy-stearicaci 12-Hydroxysteric acid Barolub fto barolubfto Cerit Fac 3 ceritfac3 Ceroxin gl ceroxingl Harwax A harwaxa Hydrofol Acid 200 hydrofolacid200 | [EINECS(EC#)]
203-366-1 | [Molecular Formula]
C18H36O3 | [MDL Number]
MFCD00004592 | [Molecular Weight]
300.48 | [MOL File]
106-14-9.mol |
Chemical Properties | Back Directory | [Description]
12-Hydroxy stearic acid (12-HSA) is a saturated hydroxy fatty acid. It's a waxy, odourless, tasteless and cream coloured compound in flakes / powder.
appearance creamish flakes or powder
melting point °C min. 70
colour Gardner max. 6
colour (on 1” Lovibond) max 20 yellow / max. 4,5 red
acid value mg KOH/g min. 175
iodine value (Wijs) g I2/100g max. 5
hydroxyl value min. 150
saponification value mg KOH/g 175 - 190 | [Appearance]
white to slightly beige powder or flakes | [Melting point ]
74-76 °C (lit.) | [Boiling point ]
180 °C | [density ]
1.0238 (rough estimate) | [refractive index ]
1.4200 (estimate) | [storage temp. ]
−20°C
| [form ]
Crystalline | [pka]
4.78±0.10(Predicted) | [color ]
White | [Water Solubility ]
Soluble in ether, alcohol and chloroform. Insoluble in water. | [BRN ]
1726730 | [Uses]
- lubrication: 12-Hydroxy stearic acid (12-HSA) gives better Lithium, Barium and Calcium multi-purpose greases. It provides excellent resistance to water, oils, solvents and crude petroleum, wide temperature range stability and high drop point.
- cosmetics: 12-HSA is used for gelling liquid Paraffin in creams and ointments, which easily liquefy on the skin. Esters of 12-HSA are used in various cosmetic products (lipsticks, deodorant and antiperspirant sticks, shaving creams, etc.).
- coatings: 12-HSA is reacted with acrylic esters to produce hard, durable thermosetting polymers used in the high quality automotive, industrial appliance and metal decorative finishes.
- rubber: functions as an activator and internal lubricant for natural and synthetic rubbers
- others: 12-HSA is an useful component in polishes, inks and hot melt adhesives
| [CAS DataBase Reference]
106-14-9(CAS DataBase Reference) | [EPA Substance Registry System]
Octadecanoic acid, 12-hydroxy- (106-14-9) |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
WI3850000
| [TSCA ]
Yes | [HS Code ]
29181990 | [Hazardous Substances Data]
106-14-9(Hazardous Substances Data) |
Hazard Information | Back Directory | [Chemical Properties]
white powder | [Definition]
ChEBI: A hydroxy fatty acid that is stearic acid bearing a hydroxy substituent at position 12. | [General Description]
Non-isothermal nucleation rate of a self-assembling fibrillar network of 12-hydroxyoctadecanoic acid (12-hydroxystearic acid) in canola oil has been reported. It is commonly used as gelling agent for organic solvents. Self-assembled monolayers of 12-hydroxyoctadecanoic acid and its 4,4′-bipyridinium salt have been observed on the solution graphite interface using scanning tunnelling microscopy. |
|
|