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ChemicalBook--->CAS DataBase List--->104372-31-8

104372-31-8

104372-31-8 Structure

104372-31-8 Structure
IdentificationMore
[Name]

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
[CAS]

104372-31-8
[Synonyms]

(1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE
(1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
(1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
(1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
(-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE
(2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
(-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE
(R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
(-)-CAMPHORSULFONYLOXAZIRIDINE
(-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee, 99+%
4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)-
(2S,8AS)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
(2S 8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE [ASYMMETRIC OXIDIZING GRADE] 98+%
(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-dioxide
(10-camphorsulfonyl)oxaziridine
(1R)-(-)-(Camphorylsulfonyl)oxaziridine, (1R)-(-)-2,N-Epoxy-exo-10,2-bornanesultam
(-)-(2S,8AR)-(Camphorylsulfonyl)oxaziridine, 98%, ee:99+%
(-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee
[Molecular Formula]

C11H17NO4S
[MDL Number]

MFCD00075428
[Molecular Weight]

259.32
[MOL File]

104372-31-8.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

170-174 °C
[alpha ]

-46.6 º (c=2, CHCl3 25 ºC)
[Boiling point ]

317.6±25.0 °C(Predicted)
[density ]

1.2486 (rough estimate)
[refractive index ]

1.5060 (estimate)
[Fp ]

170℃
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Powder
[pka]

-11.75±0.40(Predicted)
[color ]

White
[optical activity]

[α]20/D 44°, c = 2.2 in chloroform
[Usage]

A useful synthetic intermediate. Used for asymmetric hydroxylation
[BRN ]

6274369
[CAS DataBase Reference]

104372-31-8(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

10
[HS Code ]

29349990
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
[Uses]

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.
Spectrum DetailBack Directory
[Spectrum Detail]

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8)MS
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8)1HNMR
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8)IR1
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee, 99+%(104372-31-8)
[Sigma Aldrich]

104372-31-8(sigmaaldrich)
[TCI AMERICA]

(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine  [Asymmetric Oxidizing Reagent],>95.0%(T)(104372-31-8)
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