| Identification | More | [Name]
2-(Morpholinothio)benzothiazole | [CAS]
102-77-2 | [Synonyms]
2-BENZOTHIAZOLYL-N-MORPHOLINOSULFIDE
2-(MORPHOLINOTHIO)BENZOTHIAZOLE
4-(2-Benzothiazolylthio)-morpholine
AMAX
MBS
N-(2-BENZOTHIAZOLYL)THIOMORPHOLINE
NOBS
N-OXYDIETHYLENE-2-BENZOTHIAZOLESULFENAMIDE
N-OXYDIETHYLENE-2-BENZOTHIAZOLYL SULFENAMIDE
n-oxydiethylenebenzothiazole-2-sulfenamide
N-Oxydiethylene-benzothiazolesulfenamide
SANTOCURE(R) MOR
2-(4-Morpholinothio)benzothiazole
2-(4-morpholinothiobenzothiazole
2-(4-Morpholinylmercapto)benzothiazole
2-(4-Morpholinylsulfanyl)-1,3-benzothiazole
2-(4-Morpholinylthio)benzothiazole
2(4-morpholinyl-thio)-benzothiazole
2-(morpholinothio)-benzothiazol
2-(Morpholinthio)-benzothiazole | [EINECS(EC#)]
203-052-4 | [Molecular Formula]
C11H12N2OS2 | [MDL Number]
MFCD00022870 | [Molecular Weight]
252.36 | [MOL File]
102-77-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Buff to brown flakes; sweet odor. Insoluble in water; solublein benzene, acetone, methanol. | [Melting point ]
78-80°C | [Boiling point ]
413.1±55.0 °C(Predicted) | [density ]
1.34-1.40 | [vapor pressure ]
0.001Pa at 25℃ | [refractive index ]
1.5650 (estimate) | [storage temp. ]
-20°C | [solubility ]
Acetone (Slightly, Heated, Sonicated), Chloroform (Slightly) | [form ]
Solid | [pka]
1.05±0.10(Predicted) | [color ]
White to Pale Yellow | [Odor]
buff to brn. flakes, sweet odor | [biological source]
rabbit | [Contact allergens]
This rubber vulcanization accelerator belongs to the
mercaptobenzothiazole-sulfenamide group. It is used
as a chemical in the rubber industry, especially in the
production of synthetic rubber articles. It is contained
in “mercapto mix.” As a corrosion inhibitor, it can be
found in cutting fluids or in releasing fluids in the pottery
industry. It induces mainly delayed-type hypersensitivity,
but a case of immediate-type hypersensitivity
was reported in a dental assistant. | [LogP]
3.4 at 25℃ and pH7 | [Uses]
Delayed-action vulcanization accelerator. | [Dissociation constant]
-6.82-2.65 at 25℃ | [CAS DataBase Reference]
102-77-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Morpholine, 4-(2-benzothiazolylthio)-(102-77-2) | [EPA Substance Registry System]
102-77-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R43:May cause sensitization by skin contact.
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S20/21:When using, do not eat, drink or smoke .
S36:Wear suitable protective clothing .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37:Wear suitable gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24:Avoid contact with skin . | [RIDADR ]
3077 | [RTECS ]
DL5950000 | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29342000 | [Hazardous Substances Data]
102-77-2(Hazardous Substances Data) | [Toxicity]
LD50 orl-rat: 1980 mg/kg IPSTB3 3,93,76 |
| Hazard Information | Back Directory | [Description]
This rubber vulcanization accelerator is used as a
chemical in the rubber industry, especially in the
production of synthetic rubber articles. Is contained in
the "mercapto mix". As a corrosion inhibitor, it can be
found in cutting fluids or in releasing fluids in the
pottery industry. It induces mainly delayed-type
hypersensitivity, but a case of immediate-type hypersensitivity
was reported in a dental assistant.
| [Chemical Properties]
Buff to brown flakes; sweet odor. Insoluble in water; solublein benzene, acetone, methanol. | [Safety Profile]
Poison by intraperitoneal route.Moderately toxic by ingestion. Questionable carcinogenwith experimental neoplastigenic data. Experimentalteratogenic effects. An eye irritant. Mutation datareported. When heated to decomposition it emits very toxic fum |
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