| Identification | More | [Name]
Diphenyl carbonate | [CAS]
102-09-0 | [Synonyms]
AURORA 16157
CARBONIC ACID DIPHENYL ESTER
DIPHENYL CARBONATE
DPC
LABOTEST-BB LT01417418
PHENYL CARBONATE
Phenol carbonate
phenylcarbonate((pho)2co)
phenylcarbonate[(pho)2co]
Diphenyl carbonate, 99.50%
Diphenylcarbonat
Diphenyl carbonate, 99.5% | [EINECS(EC#)]
203-005-8 | [Molecular Formula]
C13H10O3 | [MDL Number]
MFCD00003037 | [Molecular Weight]
214.22 | [MOL File]
102-09-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white solid | [Melting point ]
79-82 °C (lit.) | [Boiling point ]
301-302 °C (lit.) | [density ]
1,3 g/cm3 | [vapor pressure ]
0.014Pa at 20℃ | [refractive index ]
1.5090 (estimate) | [Fp ]
168 °C
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Flakes or Crystalline Powder | [color ]
White | [Stability:]
Stable. Incompatible with strong oxidizing agents. Flammable. | [Water Solubility ]
Insoluble | [Merck ]
14,3602 | [BRN ]
1074863 | [InChIKey]
ROORDVPLFPIABK-UHFFFAOYSA-N | [CAS DataBase Reference]
102-09-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Diphenyl carbonate(102-09-0) | [EPA Substance Registry System]
102-09-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R20:Harmful by inhalation. | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
3077 | [WGK Germany ]
1
| [RTECS ]
FG0500000
| [TSCA ]
Yes | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29209010 | [Safety Profile]
Questionable
carcinogen with experimental neoplastigenic
and tumorigenic data. When heated to
decomposition it emits acrid smoke and
irritating fumes | [Hazardous Substances Data]
102-09-0(Hazardous Substances Data) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Sodium hydroxide-->Hydrogen-->Phenol-->PHOSGENE-->CARBON MONOXIDE-->calcium diphenoxide-->Vinylene carbonate-->Tetraphenylphosphonium chloride-->METHYL PHENYL CARBONATE-->phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate-->3-tert-Butylphenol-->Hexamethylene Diisocyanate | [Preparation Products]
Polycarbonate-->1,5-Diphenylcarbazide-->Diphenyl N-cyanocarbonimidate-->2,4-bis[1-(4-hydroxyphenyl)isopropyl]phenol-->4-Amino-2,4-dihydro-5-(1-methylethyl)-3H-1,2,4-triazol-3-one-->Bisphenol TMC-->1H-BenziMidazole-7-carboxylic acid, 1-[[2'-(2,5-dihydro-5-oxo-1,2,4-oxadiazol-3-yl)[1,1'-biphenyl]-4-yl]Methyl] -2-ethoxy-, Methyl ester |
| Hazard Information | Back Directory | [Chemical Properties]
white solid | [Uses]
In the molten state as solvent for nitrocellulose. | [Definition]
ChEBI: A carbonate ester that is the diphenyl ester of carbonic acid. | [Preparation]
Diphenyl carbonate is prepared by passing phosgene into a solution of
phenol in aqueous sodium hydroxide in the presence of an inert solvent such
as methylene chloride:
The organic phase, which contains the diphenyl carbonate, is separated; the
solvent is stripped off and the diphenyl carbonate is purified by distillation.
The reaction is accelerated by tertiary amines and is analogous to the
interfacial polycondensation of 2,2-bis(4'hydroxyphenyl)propane and phosgene
described. Diphenyl carbonate is a white crystalline
solid, m.p. 78??C. | [Flammability and Explosibility]
Nonflammable |
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