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ChemicalBook--->CAS DataBase List--->101469-92-5

101469-92-5

101469-92-5 Structure

101469-92-5 Structure
IdentificationMore
[Name]

N-(tert-Butoxycarbonyl)-(S)-(+)-3-pyrrolidinol
[CAS]

101469-92-5
[Synonyms]

1-PYRROLIDINECARBOXYLIC ACID, 3-HYDROXY-, 1,1-DIMETHYLETHYL ESTER, (3S)-
(3S)-(+)-N-BOC-3-HYDROXYPYRROLIDINE
BOC-(S)-3-HYDROXYPYRROLIDINE
N-BOC-(S)-3-HYDROXYPYRROLIDINE
N-T-BOC-(S)-3-HYDROXYPYRROLIDINE
N-(TERT-BUTOXYCARBONYL)-(S)-(+)-3-PYRROLIDINOL
(S)-(+)-1-BOC-3-HYDROXYPYRROLIDINE
(S)-1-BOC-3-HYDROXYPYRROLIDINE
(S)-1-BOC-3-PYRROLIDINOL
(S)-1-N-BOC-3-HYDROXYPYRROLIDINE
(S)-1-N-(T-BUTOXYCARBONYL)-3-HYDROXYPYRROLIDINE
(S)-1-N-(TERT-BUTOXYCARBONYL)-3-HYDROXYPYRROLIDINE
(S)-3-HYDROXY-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER
(S)-(+)-BOC-3-PYRROLIDINOL
(S)-N-BOC-3-HYDROXYPYRROLIDINE HYDROCHLORIDE
(S)-N-BOC-3-PYRROLIDINOL
(S)-(+)-N-(TERT-BUTOXYCARBONYL)-3-HYDROXYPYRROLIDINE
(S)-N-(TERT-BUTOXYCARBONYL)-3-HYDROXYPYRROLIDINE
(S)-TERT-BUTYL 3-HYDROXYPYRROLIDINE-1-CARBOXYLATE
(3S)-1-Boc-3-pyrrolidinol~(3S)-1-tert-Butoxycarbonyl-3-hydroxypyrrolidine
[EINECS(EC#)]

600-216-0
[Molecular Formula]

C9H17NO3
[MDL Number]

MFCD01317839
[Molecular Weight]

187.24
[MOL File]

101469-92-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

60-64 °C (lit.)
[alpha ]

26 º (c=1%, MeOH)
[Boiling point ]

273.3±33.0 °C(Predicted)
[density ]

1.142±0.06 g/cm3(Predicted)
[refractive index ]

27 ° (C=1, MeOH)
[storage temp. ]

Store at 0-5°C
[solubility ]

soluble in Methanol
[form ]

Crystalline Powder
[pka]

14.74±0.20(Predicted)
[color ]

White to pale yellow
[optical activity]

[α]20/D +26°, c = 1% in methanol
[BRN ]

6271108
[InChIKey]

APCBTRDHCDOPNY-ZETCQYMHSA-N
[CAS DataBase Reference]

101469-92-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R25:Toxic if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[F ]

10
[HazardClass ]

6.1
[PackingGroup ]

[HS Code ]

29339900
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

(S)-(+)-N-Boc-3-pyrrolidinol can be used as a reactant to synthesize:
  • tert-Butyl 3-(2-bromophenoxy)pyrrolidine-1-carboxylate, which is employed as a key intermediate in the preparation of IkB-kinase IKK2 inhibitor.
  • Dimethoxy-pyrrolidylquinazoline , and peptidomimetic quinoline derivatives.

Spectrum DetailBack Directory
[Spectrum Detail]

N-(tert-Butoxycarbonyl)-(S)-(+)-3-pyrrolidinol(101469-92-5)1HNMR
N-(tert-Butoxycarbonyl)-(S)-(+)-3-pyrrolidinol(101469-92-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(S)-(+)-N-BOC-3-pyrrolidinol, 98%(101469-92-5)
[Alfa Aesar]

(S)-(+)-1-Boc-3-hydroxypyrrolidine, 99%, ee 99%(101469-92-5)
[Sigma Aldrich]

101469-92-5(sigmaaldrich)
[TCI AMERICA]

(S)-1-(tert-Butoxycarbonyl)-3-pyrrolidinol,>98.0%(GC)(101469-92-5)
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