| Identification | More | [Name]
Platinum dichloride | [CAS]
10025-65-7 | [Synonyms]
PLATINOUS CHLORIDE
PLATINUM CHLORIDE
PLATINUM DICHLORIDE
PLATINUM(II) CHLORIDE
muriateofplatinum
platinumchloride(ptcl2)
Platinumchlorideolivebrownpowder
Platinum(II) chloride, 99.9+%
PLATINUM(II) CHLORIDE, 99.99+% METALS BASIS
PLATINUM(II) CHLORIDE, >71% PT
Platinum(II) chloride, 73% Pt
Platinum(II)chloride(99.9%-Pt)
platinum(ii) chloride, premion
PLATINUM(II) CHLORIDE: 99.9% (73%PT)
Platinous dichloride
Platinum(II) chloride, Premion(R), 99.99+% (metals basis), Pt 73% min
Platinum(II) chloride, 99.9% (metals basis), Pt 73% min
Platinum(II) chloride, Premion, 99.99+% (metals basis), Pt 73% min
Platinum(II) dichloride | [EINECS(EC#)]
233-034-1 | [Molecular Formula]
Cl2Pt | [MDL Number]
MFCD00011181 | [Molecular Weight]
265.98 | [MOL File]
10025-65-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Olive Green Crystals | [Melting point ]
581 °C (dec.)(lit.)
| [density ]
6.05 g/mL at 25 °C
| [storage temp. ]
Store below +30°C. | [solubility ]
insoluble in H2O, ethanol, ethyl ether; soluble in HCl | [form ]
Powder | [color ]
Green-brown | [Specific Gravity]
6.05 | [PH]
5-6 (H2O)suspension | [Water Solubility ]
INSOLUBLE | [crystal system]
Monoclinic | [Merck ]
14,7528 | [Space group]
C2/m | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 1.3258 | 0.3194 | 0.6802 | 90 | 107.75 | 90 | 0.2743 |
| [CAS DataBase Reference]
10025-65-7(CAS DataBase Reference) | [EPA Substance Registry System]
10025-65-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
S24:Avoid contact with skin . | [RIDADR ]
UN 3260 8/PG 3
| [WGK Germany ]
2
| [RTECS ]
TP2275000
| [F ]
21 | [TSCA ]
Yes | [HazardClass ]
8 | [HS Code ]
28439090 | [Safety Profile]
Moderately toxic by
ingestion. A skin irritant. Human mutation
data reported. When heated to
decomposition it emits toxic fumes of Cl-.
See also PLATINUM COMPOUNDS. | [Hazardous Substances Data]
10025-65-7(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 3423 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
Olive Green Crystals | [Uses]
Platinum chloride is a useful inorganic reagent which has been used in the preparation and characterization of Ru-Pt core-shell nanoparticles. | [Definition]
ChEBI: Platinum dichloride is a platinum coordination entity consisting of platinum(II) bound to two chlorine atoms. It has a role as a reagent and a catalyst. | [reaction suitability]
reagent type: catalyst
core: platinum | [Purification Methods]
It is purified by heating at 450o in a stream of Cl2 for 2hours. Some sublimation occurs because the PtCl2 sublimes completely at 560o as red (almost black) needles. This sublimate can be combined to the bulk chloride, and while still at ca 450o it should be transferred to a container and cooled in a desiccator. A probable impurity is PtCl4. To test for this add a few drops of H2O (in which PtCl4 is soluble) to the salt, filter and add an equal volume of saturated aqueous NH4Cl to the filtrate. If no precipitate is formed within 1minute, then the product is pure. If a precipitate appears, then the whole material should be washed with small volumes of H2O until the soluble PtCl4 is removed. The purified PtCl2 is partly dried by suction and then dried in a vacuum desiccator over P2O5. It is insoluble in H2O but soluble in HCl to form chloroplatinic acid (H2PtCl4) by disproportionation. [Cohen Inorg Synth VI 209 1960.] |
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