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ChemicalBook--->CAS DataBase List--->100-15-2

100-15-2

100-15-2 Structure

100-15-2 Structure
IdentificationMore
[Name]

N-Methyl-4-nitroaniline
[CAS]

100-15-2
[Synonyms]

4-METHYLAMINONITROBENZENE
4-nitro-n-methylaniline
N-METHYL-4-NITROANILINE
N-METHYL-P-NITROANILINE
P-NITRO-N-METHYLANILINE
Aniline, N-methyl-p-nitro-
Benzenamine,N-methyl-4-nitro-
n-methyl-4-nitro-benzenamin
N-methyl-4-nitro-Benzenamine
N-Methyl-N-(4-nitrophenyl)amine
N-Methyl-p-nitraniline
N-Monomethyl-p-nitroaniline
p-(Methylamino)nitrobenzene
N1-methyl-4-nitroaniline
N-METHYL-4-NITRO ANILIN
1-METHYLAMINO-4-NITROBENZENE
Nitronaniline
N-Methyl-4-nitroaniline ,99%
[EINECS(EC#)]

202-823-2
[Molecular Formula]

C7H8N2O2
[MDL Number]

MFCD00007305
[Molecular Weight]

152.15
[MOL File]

100-15-2.mol
Chemical PropertiesBack Directory
[Appearance]

brownish-yellow crystalline powder
[Melting point ]

149-151 °C(lit.)
[Boiling point ]

294.61°C (rough estimate)
[density ]

1.2010
[vapor density ]

5.25 (vs air)
[refractive index ]

1.6276 (estimate)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

0.56±0.12(Predicted)
[color ]

Yellow to Very Dark Yellow
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[Water Solubility ]

<0.1 g/100 mL at 19 ºC
[Detection Methods]

HPLC,NMR
[BRN ]

637920
[InChIKey]

XIFJZJPMHNUGRA-UHFFFAOYSA-N
[CAS DataBase Reference]

100-15-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, N-methyl-4-nitro-(100-15-2)
[EPA Substance Registry System]

100-15-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

2811
[WGK Germany ]

3
[Hazard Note ]

Highly Toxic/Irritant
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29214200
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Iodomethane-->4'-Nitroacetanilide
[Preparation Products]

6-NITROQUINOLINE-->2-Amino-5-nitrophenol-->2-Amino-5-nitrobenzophenone-->disodium 3-[[4-[[4-amino-6(or 7)-sulphonatonaphthyl]azo]phenyl]azo]-6-[(2,4-diaminophenyl)azo]-4-hydroxynaphthalene-2-sulphonate-->NITARSONE-->CHROMOTROPE 2B-->4-(4-Nitrophenyl)azoresorcinol-->DISPERSE ORANGE 3-->2-broMo-N-Methyl-N-(4-nitrophenyl)acetaMide-->5-Amino-1-methyl-2-oxoindoline-->N-methyl-2-(4-methylpiperazin-1-yl)-N-(4-nitrophenyl)acetamide
Hazard InformationBack Directory
[General Description]

Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.
[Reactivity Profile]

N-METHYL-4-NITROANILINE(100-15-2) has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.
[Air & Water Reactions]

This chemical may be sensitive to prolonged exposure to air. Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available; however, N-METHYL-4-NITROANILINE is probably combustible.
[Chemical Properties]

brownish-yellow crystalline powder
[Purification Methods]

Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Nitro-N-methylaniline(100-15-2).msds
Questions And AnswerBack Directory
[Biodegradation]

N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.
[Uses]

N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.
Spectrum DetailBack Directory
[Spectrum Detail]

N-Methyl-4-nitroaniline(100-15-2)MS
N-Methyl-4-nitroaniline(100-15-2)1HNMR
N-Methyl-4-nitroaniline(100-15-2)13CNMR
N-Methyl-4-nitroaniline(100-15-2)IR1
N-Methyl-4-nitroaniline(100-15-2)IR2
N-Methyl-4-nitroaniline(100-15-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Methyl-4-nitroaniline, 97%(100-15-2)
[Alfa Aesar]

N-Methyl-4-nitroaniline, 97%(100-15-2)
[Sigma Aldrich]

100-15-2(sigmaaldrich)
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