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ChemicalBook CAS DataBase List SODIUM P-CHLOROBENZOATE
3686-66-6

SODIUM P-CHLOROBENZOATE synthesis

8synthesis methods
-

Yield:3686-66-6 86%

Reaction Conditions:

in toluene

Steps:

8 Sodium 4-chlorobenzoate
EXAMPLE 8 Sodium 4-chlorobenzoate The procedure of Example 1 was followed using methyl 4-chlorobenzoate (4.55 g, 26.6 mmol), sodium trimethylsilanolate (2.99 g, 26.6 mmol), dry toluene (150 mL), and 4 h of heating at 80°. Sodium 4-chlorobenzoate (4.50 g, 86% yield) was isolated as a white solid: 1 H NMR (D2 O, DSS, 80 MHz) δ 7.65 ppm (ABq, Δν1-3 =29 Hz, J=8 Hz, Ar--H's, 4H).

References:

E. I. Du Pont de Nemours and Company US4723016, 1988, A

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