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ChemicalBook CAS DataBase List (S)-(-)-2,2'-Diamino-1,1'-binaphthalene
18531-95-8

(S)-(-)-2,2'-Diamino-1,1'-binaphthalene synthesis

11synthesis methods
-

Yield:18531-95-8 90%

Reaction Conditions:

with ammonia;sodium hydrogencarbonate in water at 150;Large scale;Bucherer Carbazole Synthesis;

Steps:

1.1 (1) Synthesis of 1,1'-binaphthyl-2,2'-diamine

Add 1,1'-bin-2-naphthol (5.73kg,20mol),ammonia (3.5kg, 100mol),sodium bisulfite (10.4kg, 100mol) and 25L water,reaction at 150,After the reaction,5.12 kg of 1,1'-binaphthyl-2,2'-diamine was obtained by recrystallization, with a yield of 90%.

References:

CN111606946,2020,A Location in patent:Paragraph 0027-0029

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