ChemicalBook CAS DataBase List PYRIDINE-2-D1

PYRIDINE-2-D1 synthesis

6synthesis methods

Product Name:PYRIDINE-2-D1
CAS Number:1807-97-2
Molecular formula:C5H5N
Molecular Weight:79.1

109-09-1
11 suppliers
$10.60/1gm:

1807-97-2
12 suppliers
$490.00/500mg

Yield:1807-97-2 > 98 %Chromat.

Reaction Conditions:

with triethanolamine;ethyl [2]alcohol;water-d2 for 24 h;Irradiation;Glovebox;

Steps:

2.7 General procedure of photocatalytic reactions

General procedure: A silica tube containing the catalyst, substrate (0.2 mmol), TEOA (0.9 mL), H2O (8.1 mL) and ethanol (1 mL), was sealed in a glovebox and transferred outside. Then the mixture was irradiated under the LED light (427 nm) with stirring for 24 h. Ether acetate (5 mL) was added to the mixture and the upper organic phase was collected. The yield was calculated by GC-MS with the standard curve and by NMR. For photocatalytic stability evaluation, the catalyst was re-collected by centrifugation, washed with ethanol and dried under vacuum. For deuteration, D2O and CH2CH2OD were used instead of water and ethanol.

References:

Ling, Xiang;Xu, Yangsen;Wu, Shaoping;Liu, Mofan;Yang, Peng;Qiu, Chuntian;Zhang, Guoqiang;Zhou, Hongwei;Su, Chenliang [Science China Chemistry,2020,vol. 63,# 3,p. 386 - 392]

109-04-6 Synthesis