ChemicalBook CAS DataBase List PENTACHLOROTHIOPHENOL

PENTACHLOROTHIOPHENOL synthesis

5synthesis methods

Product Name:PENTACHLOROTHIOPHENOL
CAS Number:133-49-3
Molecular formula:C6HCl5S
Molecular Weight:282.4

118-74-1 Synthesis

118-74-1
123 suppliers
$31.69/40008

133-49-3
168 suppliers
$20.00/5 g

Yield:-

Reaction Conditions:

with sodium hydroxide;sodium hydrogensulfide;concentrated aqueous hydrochloric acid in N-methyl-acetamide;water

Steps:

1.4.1 Example 1
Example 1 Hexachlorobenzene (25.0 g, 0.088 mol) was added to 50 mL of dimethylformamide followed by the addition of 7.4 g (0.096 mol) of 73% sodium hydrosulfide and 7.9 mL (0.079 mol) of 40% aqueous sodium hydroxide. The stirred reaction mixture was heated to 85° C. for 3.0 hr, cooled to room temperature, and poured into 200 mL of water. After 10 min of stirring, the insoluble material was removed by filtration, and the filtrate acidified with 15 mL (0.18 mol) of concentrated aqueous hydrochloric acid. The resulting precipitate was collected by filtration, washed with 100 mL of water, and dried in vacuo giving 22.8 g, 92% of theoretical, of pentachlorothiophenol.

References:

Uniroyal, Inc. US4461918, 1984, A

FullText

82-68-8 Synthesis