ChemicalBook CAS DataBase List N-NONANE

N-NONANE synthesis

12synthesis methods

Product Name:N-NONANE
CAS Number:111-84-2
Molecular formula:C9H20
Molecular Weight:128.26

67-66-3 Synthesis

67-66-3
6 suppliers
$33.60/500ml

38841-98-4
52 suppliers
$114.00/100ml

111-84-2
215 suppliers
$24.50/1000mg

629-78-7 Synthesis

629-78-7
189 suppliers
$15.00/25g

Yield:111-84-2 9% ，629-78-7 90.6%

Reaction Conditions:

with C₃₁H₃₇ClN₃NiO₂^(1-)*Li⁽¹⁺⁾ in tetrahydrofuran at 25; for 0.333333 h;Inert atmosphere;Overall yield = 99.6 %;

Steps:

2.5 Cross coupling of CHCl₃ and CCl₄ with Grignard reagent

General procedure: Cross-coupling reactions of Grignard reagents with CHCl₃ and CCl₄ were performed according to the following general method. Catalyst 2 (1 mg, 1.74 μmol) in 1 mL THF was added using a gas-tight syringe to a 5 mL round bottom flask purged with N₂. To this solution 2 M n-butylmagnesium chloride in THF (0.63 mL, 1.26 mmol) was added. CHCl₃ (34 μL, 0.42 mmol) was added to the reaction mixture. In the case of reactions with CCl₄ (40 μL, 0.42 mmol), 1.68 mmol of Grignard reagent was added. Samples were collected for analysis after 20 min. At the end of the reaction, excess Grignard reagent was destroyed using methanol and the reaction products were analyzed by GC-MS using an internal standard to quantify product formation.

References:

Gartia, Yashraj;Nasini, Udaya Bhasker;Ghosh, Anindya;Biswas, Abhijit;Stadler, Matthew [Journal of Molecular Catalysis A: Chemical,2012,vol. 363-364,p. 322 - 327,6]