ChemicalBook CAS DataBase List Methyl 4-methylbenzoate

Methyl 4-methylbenzoate synthesis

15synthesis methods

Product Name:Methyl 4-methylbenzoate
CAS Number:99-75-2
Molecular formula:C9H10O2
Molecular Weight:150.17

67-56-1 Synthesis

67-56-1
743 suppliers
$7.29/5ml-f

104-87-0 Synthesis

104-87-0
504 suppliers
$6.00/25g

99-75-2
271 suppliers
$6.00/10g

106-44-5 Synthesis

106-44-5
473 suppliers
$14.00/5g

Yield:99-75-2 75% ，106-44-5 15%

Reaction Conditions:

with diphenyl diselenide;dihydrogen peroxide at 50; for 2 h;Green chemistry;

Steps:

3.3. General Procedure for the Synthesis of Esters 6
General procedure: Diphenyl diselenide (3, 0.006 g; 0.02 mmol) was treated with H2O2 (30%·w/w, 0.15 mL, 1.5 mmol)and stirred at room temperature until the discoloration of the reaction mixture. Then, the aldehyde 1(1 mmol) and the appropriate alcohol (2.5 mmol) were added. The reaction mixture was stirred at50 °C for 2 h and extracted three times with EtOAc (3 × 20 mL). The collected organic layers were driedover Na2SO4 and the solvent evaporated under reduced pressure.

References:

Sancineto, Luca;Tidei, Caterina;Bagnoli, Luana;Marini, Francesca;Lenardo, Eder J.;Santi, Claudio [Molecules,2015,vol. 20,# 6,p. 10496 - 10510]

67-56-1 Synthesis

67-56-1
743 suppliers
$7.29/5ml-f

201230-82-2 Synthesis