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4253-99-0

DI-N-AMYL SULFOXIDE synthesis

2synthesis methods
-

Yield:-

Reaction Conditions:

with C42H30Fe2N6O6*C2H6O;urea hydrogen peroxide adduct in acetonitrile at 20; for 0.25 h;

Steps:

2.3. Catalytic sulfoxidation

General procedure: 0.2 mmol UHP as an oxidant was added slowly to a stirringsolution of 1 ml of CH3CN containing the complex [Fe2(salcyn)3],a substrate (0.2 mmol) and chlorobenzene (0.2 mmol) as an internalstandard. Stirring was continued for 15 min at room temperaturein a closed system. The reaction progress was monitored by GC. Assignments of the products were made by comparison with authentic samples.

References:

Akbari, Ali;Amini, Mojtaba;Bagherzadeh, Mojtaba;Ellern, Arkady;Mesbahi, Elnaz;Woo, L. Keith [Polyhedron,2020,vol. 183]

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