chlorotris(2-methyl-2-phenylpropyl)stannane synthesis
- Product Name:chlorotris(2-methyl-2-phenylpropyl)stannane
- CAS Number:1178-79-6
- Molecular formula:C30H39ClSn
- Molecular Weight:553.7936
7646-78-8
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35293-35-7
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14208-42-5
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Yield:14208-42-5 71%
Reaction Conditions:
in diethyl ether;toluene;1.44M Et2O soln. of NeophMgCl (1.7-2.05 equiv.) dropwise with stirring added to toluene soln. of SnCl4 (1 equiv.) under N2 at room temp., heatedat reflux for 3 h, left at room temp. for 12 h; aq. satd. soln. NH4Cl added, organic layer separated, aq. layer extracted with Et2O, combined organic extracts dried over MgSO4, solvent removedunder vac., recrystd. from n-heptane; ratio of Nph3SnCl/Nph2SnCl2 was 6 0/40-24.5/75.5, NMR;
References:
Zú?iga, Adriana E.;Fidelibus, Pablo M.;Mandolesi, Sandra D.;Podestá, Julio C. [Journal of Organometallic Chemistry,2011,vol. 696,# 8,p. 1547 - 1555]
7646-78-8
306 suppliers
$11.00/5g
35293-35-7
39 suppliers
$120.00/100ml
1178-79-6
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1262-78-8
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13356-08-6
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$31.89/250mg
1178-79-6
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7647-01-0
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$10.00/10g
13356-08-6
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$31.89/250mg
1178-79-6
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