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ChemicalBook CAS DataBase List 3-Amino-cyclopent-2-enone
28566-12-3

3-Amino-cyclopent-2-enone synthesis

3synthesis methods
-

Yield: 100%

Reaction Conditions:

with ammonium hydroxide in ethanol at 85; for 16 h;

Steps:

2.1.A 3-Aminocyclopent-2-en-1-one
3-Aminocyclopent-2-en-1-one
27.5 ml of aqueous ammonia solution (28%) were added to a solution of 5.5 g (43.6 mmol) of 3-ethoxy-2-cyclopenten-1-one in 55 ml of ethanol, and the mixture was stirred at 85° C. for 16 h.
After cooling to RT, the reaction mixture was concentrated under reduced pressure and dried. Yield: 4.2 g (quant.)
GC/MS [Method 5]: Rt=4.78 min; MS (EI): m/z=97.

References:

BAYER PHARMA AKTIENGESELLSCHAFT;R?HRIG, Susanne;HILLISCH, Alexander;STRA?BURGER, Julia;HEITMEIER, Stefan;SCHMIDT, Martina Victoria;SCHLEMMER, Karl-Heinz;BUCHMüLLER, Anja;GERDES, Christoph;TELLER, Henrik;SCH?FER, Martina;TERSTEEGEN, Adrian US2016/152613, 2016, A1 Location in patent:Paragraph 0328-0330

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