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ChemicalBook CAS DataBase List 3-Amino-5-mercapto-1,2,4-triazole
16691-43-3

3-Amino-5-mercapto-1,2,4-triazole synthesis

2synthesis methods
3-Amino-5-mercapto-1,2,4-triazole can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly in laboratory research and development process and chemical production process. A method for synthesizing 3-amino-5-mercapto-1,2,4-triazole, which is characterized by reacting guanidine with heating, and is particularly characterized by reacting an aminoguanidine salt with a thiocyanate salt. 
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Yield:-

Reaction Conditions:

with sodium hydroxide in water; for 3 h;Reflux;

Steps:

General procedure for synthesis of 2-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylthio)acetohydrazide (6)

(2) NaOH (225g, 5.62mol) was dissolved in water (960mL). 2 was then added and the solution was refluxed for 3h. After cooling, the pH value of the solution was adjusted to 1 using hydrochloric acid. After that the solid was precipitated and recrystallization from methanol gave 3 as colorless crystals.

References:

Luo, Yin;Zhang, Shuai;Liu, Zhi-Jun;Chen, Wu;Fu, Jie;Zeng, Qing-Fu;Zhu, Hai-Liang [European Journal of Medicinal Chemistry,2013,vol. 64,p. 54 - 61]

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