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ChemicalBook CAS DataBase List 2-amino-6-methylpyridin-3-ol
20348-16-7

2-amino-6-methylpyridin-3-ol synthesis

2synthesis methods
-

Yield:20348-16-7 99%

Reaction Conditions:

palladium on activated carbon in ethyl acetate;

Steps:

56.a a

a 2-Amino-6-methyl-pyridin-3-ol A mixture of 6-methyl-2-nitro-pyridin-3-ol (18.5 g, 0.120 mmol), 10% palladium on activated carbon (1.35 g), and ethyl acetate (240 mL) was hydrogenated for 3 days. The mixture was filtered through Celite and washed with methanol/ethylacetate (5%). The filtrate and washing were combined and concentrated to give the title compound (14.7 g, 99% yield) as a pale brown solid. 1H NMR (DMSO-d6) δ9.19 (bs, 1H), 6.73 (d, 1H, J=7.6 Hz), 6.12 (d, 1H, J=7.6 Hz), 5.36 (bs, 2H), 2.15 (s, 3H).

References:

US2002/169200,2002,A1

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