ChemicalBook CAS DataBase List 1-Bromo-4-iodobenzene

1-Bromo-4-iodobenzene synthesis

14synthesis methods

Product Name:1-Bromo-4-iodobenzene
CAS Number:589-87-7
Molecular formula:C6H4BrI
Molecular Weight:282.9

4-BROMOBENZENEDIAZONIUM TETRAFLUOROBORATE

673-40-5
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$52.00/5g

589-87-7
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$10.00/1g

Yield:589-87-7 99%

Reaction Conditions:

with potassium iodide in water at 25; for 0.0833333 h;Sandmeyer Reaction;Solvent;

Steps:

3.2. General Procedure for Synthesis of Aryl Iodides (2)from Aryl Diazofluoroborates

General procedure: To a suspension of aryl diazofluoroborate (1 mmol) inwater (3mL), aqueous solution of potassium iodide (1.5 mmol in 2mL H2O) was added in single lot at room temperature.Reaction mixture was stirred for specific time (Table 2).The solid product was separated by filtration and the liquidproducts were separated by extraction in diethyl ether (5mL).The organic layer was dried over anhydrous Na2SO4 andsolvent was removed at room temperature afforded pure iodocompounds in excellent yields. Further all synthesized compoundswere characterized and confirmed by comparisonwith reported aryl iodides.

References:

Gholap, Somnath S. [Letters in Organic Chemistry,2018,vol. 15,# 7,p. 594 - 599]

106-40-1 Synthesis