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ChemicalBook >> CAS DataBase List >> MAGNESIUM METHOXIDE

MAGNESIUM METHOXIDE

MAGNESIUM METHOXIDE price.
  • $23.7 - $143
  • Product name: MAGNESIUM METHOXIDE
  • CAS: 109-88-6
  • MF: C2H6MgO2
  • MW: 86.37
  • EINECS:203-715-8
  • MDL Number:MFCD00053671
  • Synonyms:Magnesium methoxide 7-8% in methanol;MAGNESIUM METHOXIDE, CA. 6-10 WT. % SOLU TION IN METHANOL;MAGNESIUM METHYLATE POWDER 7-8% IN METHANOL;MAGNESIUM METHOXIDE POWDER 95%;magnesium methoxide solution;Dimethoxymagnesium;Magnesium bismethoxide;Magnesium dimethanolate
5 prices
Selected condition：
Brand
  • Alfa Aesar
  • Sigma-Aldrich
Package
  • 250g
  • 500ml
  • 1kg
  • 2l
  • 2kg
  • ManufacturerAlfa Aesar
  • Product number040448
  • Product descriptionMagnesium methoxide, 7-8% in methanol
  • Packaging250g
  • Price$23.7
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number040448
  • Product descriptionMagnesium methoxide, 7-8% in methanol
  • Packaging1kg
  • Price$61.9
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number040448
  • Product descriptionMagnesium methoxide, 7-8% in methanol
  • Packaging2kg
  • Price$76.65
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number335657
  • Product descriptionMagnesium methoxide solution 6-10wt. % in methanol
  • Packaging500ml
  • Price$90.5
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number335657
  • Product descriptionMagnesium methoxide solution 6-10wt. % in methanol
  • Packaging2l
  • Price$143
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 040448 Magnesium methoxide, 7-8% in methanol 250g $23.7 2024-03-01 Buy
Alfa Aesar 040448 Magnesium methoxide, 7-8% in methanol 1kg $61.9 2024-03-01 Buy
Alfa Aesar 040448 Magnesium methoxide, 7-8% in methanol 2kg $76.65 2024-03-01 Buy
Sigma-Aldrich 335657 Magnesium methoxide solution 6-10wt. % in methanol 500ml $90.5 2024-03-01 Buy
Sigma-Aldrich 335657 Magnesium methoxide solution 6-10wt. % in methanol 2l $143 2024-03-01 Buy

Properties

Density :0.816 g/mL at 25 °C
vapor pressure :17kPa at 25℃
refractive index :n20/D 1.3381
Flash point :46 °F
solubility :Chloroform (Soluble), Methanol (Soluble), Water (Soluble)
form :Liquid
Specific Gravity :0.815
Water Solubility :Decomposes in water.
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Sensitive :Moisture Sensitive
Exposure limits :ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) Stability :Hygroscopic, Moisture sensitive
LogP :0.77 at 20℃
CAS DataBase Reference :109-88-6(CAS DataBase Reference)
EPA Substance Registry System :Methanol, magnesium salt (109-88-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Description

The use of magnesium methoxide for the deprotection of alkyl esters is described. This mild reagent provides a good method to cleave esters efficiently and more importantly, allows for effective differentiation between two different esters. Dimethyl carbonate is synthesized directly from carbon dioxide and methanol in the presence of magnesium methoxide. 20 mol% DEA additions to magnesium methoxide showed enhanced stability such that a time-dependent change in the sol was not observed in air. Also enhanced the crystallization process.

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