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ChemicalBook >> CAS DataBase List >> (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide

(S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide

(S)-VAPOL  phosphoric  acid,  (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl  phosphate,  (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide price.
  • $95 - $945
  • Product name: (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide
  • CAS: 871130-17-5
  • MF: C40H25O4P
  • MW: 600.6
  • EINECS:
  • MDL Number:MFCD09265084
  • Synonyms:(S)-VAPOL hydrogenphosphate;(S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide;8,9-Diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepin-18-ol 18-oxide;(S)-VAPOL Hydrogen Phosphate,99%e.e.;(8aS)-18-Hydroxy-8,9-diphenyl-18-oxide-diphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepin;(S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d;3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide;Diphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepin, 18-hydroxy-8,9-diphenyl-, 18-oxide, (8aS)-
8 prices
Selected condition:
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 25mg
  • 50MG
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • ManufacturerAmbeed
  • Product numberA671122
  • Product description(8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+%
  • Packaging100mg
  • Price$165
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA671122
  • Product description(8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+%
  • Packaging250mg
  • Price$300
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA671122
  • Product description(8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+%
  • Packaging1g
  • Price$945
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0030601
  • Product description(R)-(-)-VAPOL HYDROGENPHOSPHATE 95.00%
  • Packaging50MG
  • Price$311.85
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number688320
  • Product description(S)-VAPOL hydrogenphosphate
  • Packaging100mg
  • Price$112.2
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number688320
  • Product description(S)-VAPOL hydrogenphosphate
  • Packaging500mg
  • Price$543
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-8555
  • Product description(S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide
  • Packaging25mg
  • Price$95
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-8555
  • Product description(S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide
  • Packaging100mg
  • Price$324
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A671122 (8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+% 100mg $165 2021-12-16 Buy
Ambeed A671122 (8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+% 250mg $300 2021-12-16 Buy
Ambeed A671122 (8aS)-18-Hydroxy-8,9-diphenyldiphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepine18-oxide 98+% 1g $945 2021-12-16 Buy
American Custom Chemicals Corporation CCH0030601 (R)-(-)-VAPOL HYDROGENPHOSPHATE 95.00% 50MG $311.85 2021-12-16 Buy
Sigma-Aldrich 688320 (S)-VAPOL hydrogenphosphate 100mg $112.2 2024-03-01 Buy
Sigma-Aldrich 688320 (S)-VAPOL hydrogenphosphate 500mg $543 2024-03-01 Buy
Strem Chemicals 15-8555 (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide 25mg $95 2024-03-01 Buy
Strem Chemicals 15-8555 (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide 100mg $324 2024-03-01 Buy

Properties

Melting point :>400 °C
Density :1.44±0.1 g/cm3(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :1.13±0.20(Predicted)
optical activity :[α]22/D +412°, c = 1 in chloroform

Safety Information

Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:

Description

Catalyst for:
  • Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide
  • Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols
  • Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening
  • Highly enantioselective addition of imides to imines to give aminals
  • Friedel-Crafts reaction of pyrroles with benzylidenebenzamides