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ChemicalBook >> CAS DataBase List >> (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE price.
  • $40 - $499.94
  • Product name: (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
  • CAS: 85134-98-1
  • MF: C21H37BO
  • MW: 316.33
  • EINECS:
  • MDL Number:MFCD00074809
  • Synonyms:(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE;(+)-DIISOPINOCAMPHEYLMETHOXYBORANE;)-B-Methoxydiisopinocampheylborane;methoxy-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane;Borinic acid, B,B-bis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester;()-B-Methoxydiisopinocampheylborane;(-)-B-Methoxydiisopinocampheylborane hydrate;()-B-Methoxydiisopinocampheylborane hydrate
5 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • TRC
Package
  • 5MG
  • 100mg
  • 5g
  • 25g
  • 100g
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0004000
  • Product description(-)-BETA-METHOXYDIISOPINOCAMPHEYLBORANE 95.00%
  • Packaging5MG
  • Price$499.94
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number317047
  • Product description(?)-B-Methoxydiisopinocampheylborane
  • Packaging5g
  • Price$200
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number317047
  • Product description(?)-B-Methoxydiisopinocampheylborane
  • Packaging100g
  • Price$391.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number317047
  • Product description(?)-B-Methoxydiisopinocampheylborane
  • Packaging25g
  • Price$426
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberM269740
  • Product description(-)-B-Methoxydiisopinocampheylboranehydrate
  • Packaging100mg
  • Price$40
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation BOR0004000 (-)-BETA-METHOXYDIISOPINOCAMPHEYLBORANE 95.00% 5MG $499.94 2021-12-16 Buy
Sigma-Aldrich 317047 (?)-B-Methoxydiisopinocampheylborane 5g $200 2023-06-20 Buy
Sigma-Aldrich 317047 (?)-B-Methoxydiisopinocampheylborane 100g $391.8 2024-03-01 Buy
Sigma-Aldrich 317047 (?)-B-Methoxydiisopinocampheylborane 25g $426 2024-03-01 Buy
TRC M269740 (-)-B-Methoxydiisopinocampheylboranehydrate 100mg $40 2021-12-16 Buy

Properties

Boiling point :365.6±9.0 °C(Predicted)
Density :0.95±0.1 g/cm3(Predicted)
Flash point :>230 °F
storage temp. :2-8°C
optical activity :[α]20/D 72±3°, c = 1% in diethyl ether

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(-)-B-Methoxydiisopinocampheylborane is a very useful reactant involved in organic synthesis reactions. It has been used in double allylboration for synthesis of fragments of tetrafibricin, anticancer cytotoxic monorhizopodin synthesis, annulation of cyclic allylsilanes, and asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs.

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