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ChemicalBook >> CAS DataBase List >> (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

$65 - $2785
Product name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS: 791616-62-1
MF: C36H17F12O4P
MW: 772.47
EINECS:
MDL Number:MFCD08689863
Synonyms:(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS;(R)-3,3μ-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1μ-bi-2-naphthol cyclic monophosphate, (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide;(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-;(11BR)-2,6-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-4-HYDROXY-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE);2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

Price13 Properties Safety Information Description

13 prices

Brand

AK Scientific
Ambeed
Biosynth Carbosynth
Matrix Scientific
Sigma-Aldrich
Strem Chemicals

Package

25mg
50mg
100mg
250mg
500mg
1g

ManufacturerAK Scientific
Product number4711BB
Product description(S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Packaging1g
Price$2785
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA313663
Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee
Packaging100mg
Price$78
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA313663
Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee
Packaging250mg
Price$158
Updated2021-12-16
Buy

ManufacturerBiosynth Carbosynth
Product numberFB103049
Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging25mg
Price$65
Updated2021-12-16
Buy

ManufacturerBiosynth Carbosynth
Product numberFB103049
Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging50mg
Price$100
Updated2021-12-16
Buy

ManufacturerBiosynth Carbosynth
Product numberFB103049
Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging100mg
Price$170
Updated2021-12-16
Buy

ManufacturerBiosynth Carbosynth
Product numberFB103049
Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging250mg
Price$400
Updated2021-12-16
Buy

ManufacturerBiosynth Carbosynth
Product numberFB103049
Product description(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging500mg
Price$750
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number118696
Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
Packaging250mg
Price$713
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number118696
Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
Packaging500mg
Price$1238
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number118696
Product description(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%
Packaging1g
Price$2026
Updated2021-12-16
Buy

ManufacturerSigma-Aldrich
Product number674605
Product description(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%
Packaging100mg
Price$189
Updated2024-03-01
Buy

ManufacturerStrem Chemicals
Product number15-1366
Product description(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
Packaging100mg
Price$127
Updated2024-03-01
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
AK Scientific	4711BB	(S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate	1g	$2785	2021-12-16	Buy
Ambeed	A313663	(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee	100mg	$78	2021-12-16	Buy
Ambeed	A313663	(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 98%99%ee	250mg	$158	2021-12-16	Buy
Biosynth Carbosynth	FB103049	(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide	25mg	$65	2021-12-16	Buy
Biosynth Carbosynth	FB103049	(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide	50mg	$100	2021-12-16	Buy
Biosynth Carbosynth	FB103049	(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide	100mg	$170	2021-12-16	Buy
Biosynth Carbosynth	FB103049	(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide	250mg	$400	2021-12-16	Buy
Biosynth Carbosynth	FB103049	(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide	500mg	$750	2021-12-16	Buy
Matrix Scientific	118696	(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%	250mg	$713	2021-12-16	Buy
Matrix Scientific	118696	(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%	500mg	$1238	2021-12-16	Buy
Matrix Scientific	118696	(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.0%	1g	$2026	2021-12-16	Buy
Sigma-Aldrich	674605	(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 95%	100mg	$189	2024-03-01	Buy
Strem Chemicals	15-1366	(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)	100mg	$127	2024-03-01	Buy

Properties

Melting point :162-175 °C
Boiling point :722.1±70.0 °C(Predicted)
Density :1.63±0.1 g/cm3(Predicted)
storage temp. :2-8°C
form :Powder
pka :1.09±0.20(Predicted)
color :white to light-yellow
optical activity :[α]20/D -220°, c = 1 in chloroform (typical)
InChIKey :DQORDVSQWPKAQJ-UHFFFAOYSA-N

Safety Information

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P264	Wash hands thoroughly after handling.
P264	Wash skin thouroughly after handling.
P271	Use only outdoors or in a well-ventilated area.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352	IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

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Suppliers and manufacturers

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Properties

Safety Information

Description

Related product price

Suppliers and manufacturers