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ChemicalBook >> CAS DataBase List >> [Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene price.
  • $6 - $1216.22
  • Product name: [Bis(trifluoroacetoxy)iodo]benzene
  • CAS: 2712-78-9
  • MF: C10H5F6IO4
  • MW: 430.04
  • EINECS:220-308-0
  • MDL Number:MFCD00009672
  • Synonyms:IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE);IODINE, PHENYLBIS(TRIFLUOROACETATO)-;IODOBENZENE BIS(TRIFLUOROACETATE);IODOBENZENE I,I-BIS(TRIFLUOROACETATE);BIS(TRIFLUORACETOXY)- IODOBENZENE;[BIS(TRIFLUOROACETOXY)IODO]BENZENE;[Bis(trifluoroacetoxy)](phenyl)iodane;Iodobenzene 1,1-bis(trifluoroacetate)
39 prices
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  • Acrotein
  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Chem-Impex
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  • Matrix Scientific
  • Oakwood
  • ProChem
  • Sigma-Aldrich
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Package
  • 5g
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  • 50g
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  • 250g
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  • 1kg
  • ManufacturerAcrotein
  • Product numberAC-3420
  • Product description[Bis(trifluoroacetoxy)iodo]benzene 97%
  • Packaging100g
  • Price$113.3
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90267
  • Product description[Bis(trifluoroacetoxy)iodo]benzene
  • Packaging5g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90267
  • Product description[Bis(trifluoroacetoxy)iodo]benzene
  • Packaging25g
  • Price$20
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL15141
  • Product description[Bis(trifluoroacetoxy)iodo]benzene, 97%
  • Packaging5g
  • Price$45.8
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL15141
  • Product description[Bis(trifluoroacetoxy)iodo]benzene, 97%
  • Packaging25g
  • Price$118
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging10g
  • Price$9
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging25g
  • Price$16
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging100g
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging500g
  • Price$216
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA604530
  • Product description(Bis(trifluoroacetoxy)iodo)benzene 97%
  • Packaging1kg
  • Price$411
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0014844
  • Product descriptionBIS(TRIFLUORACETOXY)- IODOBENZENE 95.00%
  • Packaging5G
  • Price$800.42
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0014844
  • Product descriptionBIS(TRIFLUORACETOXY)- IODOBENZENE 95.00%
  • Packaging25G
  • Price$1216.22
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB49107
  • Product description[Bis(trifluoroacetoxy)iodo]benzene
  • Packaging50g
  • Price$50
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB49107
  • Product description[Bis(trifluoroacetoxy)iodo]benzene
  • Packaging100g
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB49107
  • Product description[Bis(trifluoroacetoxy)iodo]benzene
  • Packaging250g
  • Price$200
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-3420 [Bis(trifluoroacetoxy)iodo]benzene 97% 100g $113.3 2021-12-16 Buy
AK Scientific J90267 [Bis(trifluoroacetoxy)iodo]benzene 5g $10 2021-12-16 Buy
AK Scientific J90267 [Bis(trifluoroacetoxy)iodo]benzene 25g $20 2021-12-16 Buy
Alfa Aesar L15141 [Bis(trifluoroacetoxy)iodo]benzene, 97% 5g $45.8 2024-03-01 Buy
Alfa Aesar L15141 [Bis(trifluoroacetoxy)iodo]benzene, 97% 25g $118 2024-03-01 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 5g $6 2021-12-16 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 10g $9 2021-12-16 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 25g $16 2021-12-16 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 100g $45 2021-12-16 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 500g $216 2021-12-16 Buy
Ambeed A604530 (Bis(trifluoroacetoxy)iodo)benzene 97% 1kg $411 2021-12-16 Buy
American Custom Chemicals Corporation HCH0014844 BIS(TRIFLUORACETOXY)- IODOBENZENE 95.00% 5G $800.42 2021-12-16 Buy
American Custom Chemicals Corporation HCH0014844 BIS(TRIFLUORACETOXY)- IODOBENZENE 95.00% 25G $1216.22 2021-12-16 Buy
Biosynth Carbosynth FB49107 [Bis(trifluoroacetoxy)iodo]benzene 50g $50 2021-12-16 Buy
Biosynth Carbosynth FB49107 [Bis(trifluoroacetoxy)iodo]benzene 100g $90 2021-12-16 Buy
Biosynth Carbosynth FB49107 [Bis(trifluoroacetoxy)iodo]benzene 250g $200 2021-12-16 Buy

Properties

Melting point :121-125 °C(lit.)
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form :Crystalline Powder
color :White to pale yellow
Water Solubility :insoluble
Sensitive :Moisture & Light Sensitive
BRN :764767
Stability :Air and Moisture Sensitive
CAS DataBase Reference :2712-78-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

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