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ChemicalBook >> CAS DataBase List >> t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3 price.
  • $31 - $1702
  • Product name: t-BuBrettPhos Palladacycle Gen. 3
  • CAS: 1536473-72-9
  • MF: C44H63NO5PPdS-
  • MW: 855.433481
  • EINECS:-0
  • MDL Number:MFCD25976528
  • Synonyms:Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3];t-BuBrettPhos Palladacycle Gen. 3;Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3];Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.;Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II);[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle
26 prices
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  • Alichem
  • Ambeed
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  • Crysdot
  • Sigma-Aldrich
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  • 100mg
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  • ManufacturerAlichem
  • Product number1536473729
  • Product descriptiontBuBrettPhosPdG3
  • Packaging5g
  • Price$856.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA206000
  • Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
  • Packaging100mg
  • Price$31
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA206000
  • Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
  • Packaging250mg
  • Price$76
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA206000
  • Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
  • Packaging1g
  • Price$153
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA206000
  • Product description[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97%
  • Packaging5g
  • Price$620
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY073202
  • Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
  • Packaging250mg
  • Price$70
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY073202
  • Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
  • Packaging1g
  • Price$195
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY073202
  • Product descriptionMethanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97%
  • Packaging5g
  • Price$750
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM102765
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
  • Packaging10g
  • Price$1702
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM102765
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
  • Packaging5g
  • Price$1021
  • Updated2021-12-16
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  • ManufacturerChemenu
  • Product numberCM102765
  • Product descriptionMethanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95%
  • Packaging1g
  • Price$341
  • Updated2021-12-16
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  • ManufacturerCrysdot
  • Product numberCD52001017
  • Product descriptiontBuBrettPhosPdG3 95+%
  • Packaging250mg
  • Price$109
  • Updated2021-12-16
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  • ManufacturerCrysdot
  • Product numberCD52001017
  • Product descriptiontBuBrettPhosPdG3 95+%
  • Packaging1g
  • Price$279
  • Updated2021-12-16
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  • ManufacturerCrysdot
  • Product numberCD52001017
  • Product descriptiontBuBrettPhosPdG3 95+%
  • Packaging5g
  • Price$835
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number928313
  • Product descriptiontBuBrettPhos Pd G3 ChemBeads
  • Packaging1G
  • Price$287
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number745979
  • Product descriptiontBuBrettPhos Pd G3 96%
  • Packaging100MG
  • Price$81.6
  • Updated2024-03-01
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Manufacturer Product number Product description Packaging Price Updated Buy
Alichem 1536473729 tBuBrettPhosPdG3 5g $856.8 2021-12-16 Buy
Ambeed A206000 [(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97% 100mg $31 2021-12-16 Buy
Ambeed A206000 [(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97% 250mg $76 2021-12-16 Buy
Ambeed A206000 [(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97% 1g $153 2021-12-16 Buy
Ambeed A206000 [(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II)methanesulfonate 97% 5g $620 2021-12-16 Buy
Arctom SY073202 Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97% 250mg $70 2021-12-16 Buy
Arctom SY073202 Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97% 1g $195 2021-12-16 Buy
Arctom SY073202 Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥97% 5g $750 2021-12-16 Buy
Chemenu CM102765 Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95% 10g $1702 2021-12-16 Buy
Chemenu CM102765 Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95% 5g $1021 2021-12-16 Buy
Chemenu CM102765 Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II) 95% 1g $341 2021-12-16 Buy
Crysdot CD52001017 tBuBrettPhosPdG3 95+% 250mg $109 2021-12-16 Buy
Crysdot CD52001017 tBuBrettPhosPdG3 95+% 1g $279 2021-12-16 Buy
Crysdot CD52001017 tBuBrettPhosPdG3 95+% 5g $835 2021-12-16 Buy
Sigma-Aldrich 928313 tBuBrettPhos Pd G3 ChemBeads 1G $287 2024-03-01 Buy
Sigma-Aldrich 745979 tBuBrettPhos Pd G3 96% 100MG $81.6 2024-03-01 Buy

Properties

Melting point :119-131°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
color :brown-green
InChIKey :VKLHIPFGYVFUGT-UHFFFAOYSA-N
CAS DataBase Reference :1536473-72-9

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

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