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RSC Advances

IF: 3.89
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Novel choline-chloride-based deep-eutectic-solvents with renewable hydrogen bond donors: levulinic acid and sugar-based polyols

Published:18 November 2011 DOI: 10.1039/C1RA00630D
Zaira Maugeri and Pablo Domínguez de María

Abstract

Choline chloride (ChCl) has been combined with renewable hydrogen bond donors (HBD) to form novel deep eutectic solvents (DES) with melting points lower than 100 °C. In some cases (e.g. sorbitol or isosorbide as HBDs) chiral DES can be easily produced. Moreover, the addition of glycerol decreases the viscosity of DES significantly. In the ChCl?:?levulinic acid DES case, singular properties were observed. Thus, equimolecular mixtures of ChCl?:?levulinic acid (1?:?1) formed a crystal at room temperature, rapidly melting in contact with air humidity. Addition of excess of acetone to ChCl?:?levulinic acid (1?:?2) leads to the almost quantitative precipitation of choline chloride, which can be used again to form a DES.

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Related products
Procduct Name CAS Molecular Formula Supplier Price
Glycerol 56-81-5 C3H8O3 1785 suppliers $5.00-$6250.00
Choline chloride 67-48-1 C5H14ClNO 838 suppliers $9.00-$3132.00
Sorbitol 50-70-4 C6H14O6 831 suppliers $5.00-$2150.00
Levulinic acid 123-76-2 C5H8O3 561 suppliers $5.00-$2420.88
Isosorbide 652-67-5 C6H10O4 455 suppliers $5.00-$2395.30
ChCl:2EG - Inquiry

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