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α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル

α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 化學構(gòu)造式
17659-49-3
CAS番號.
17659-49-3
化學名:
α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル
別名:
α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル;6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 3-ヒドロキシ-2-フェニルプロパノアート
英語名:
Anisodamine
英語別名:
ANISODAMINE;ANISODAMINE;LAnisodaMine;ANISODAMINE USP/EP/BP;Anisodamine Intermediate;Hyoscyamine Sulfate Impurity 8;Tropic acid 6-hydroxy-3-tropanyl ester;Racanisodamine, 98%, from Anisodus tanguticus;Anisodamine|||7β-Hydroxyhyoscyamine|||Raceanisodamine;Tropic Acid 6-Hydroxy-3-tropanyl Ester discontinued, see H942900
CBNumber:
CB6354310
化學式:
C17H23NO4
分子量:
305.37
MOL File:
17659-49-3.mol

α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 物理性質(zhì)

融點 :
106-109°C
沸點 :
474.6±45.0 °C(Predicted)
比重(密度) :
1.27
貯蔵溫度 :
Sealed in dry,Room Temperature
溶解性:
クロロホルム(微量)、DMSO(微量)、メタノール(微量)
外見 :
個體
酸解離定數(shù)(Pka):
14.12±0.10(Predicted)
色:
白い
安全性情報
  • リスクと安全性に関する聲明
  • 危険有害性情報のコード(GHS)
HSコード  29399990
絵表示(GHS) GHS hazard pictograms
注意喚起語 警告
危険有害性情報
コード 危険有害性情報 危険有害性クラス 區(qū)分 注意喚起語 シンボル P コード
H227 引火性液體 引火性液體 4 警告 P210, P280, P370+P378, P403+P235,P501
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
注意書き
P210 熱/火花/裸火/高溫のもののような著火源から遠ざ けること。-禁煙。
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P280 保護手袋/保護衣/保護眼鏡/保護面を著用するこ と。
P302+P352 皮膚に付著した場合:多量の水と石鹸で洗うこと。
P305+P351+P338 眼に入った場合:水で數(shù)分間注意深く洗うこと。次にコ ンタクトレンズを著用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P332+P313 皮膚刺激が生じた場合:醫(yī)師の診斷/手當てを受けるこ と。
P337+P313 眼の刺激が続く場合:醫(yī)師の診斷/手當てを受けること。
P370+P378 火災の場合:消火に...を使用すること。
P403+P235 換気の良い場所で保管すること。涼しいところに 置くこと。
P501 內(nèi)容物/容器を...に廃棄すること。

α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 価格 もっと(5)

メーカー 製品番號 製品説明 CAS番號 包裝 価格 更新時間 購入
富士フイルム和光純薬株式會社(wako) W01COBQV-4395
6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
17659-49-3 1g ¥15000 2024-03-01 購入
富士フイルム和光純薬株式會社(wako) W01COBQV-4395
6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
17659-49-3 5g ¥50000 2024-03-01 購入
富士フイルム和光純薬株式會社(wako) W01COBQV-4395
6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
17659-49-3 10g ¥80000 2024-03-01 購入
富士フイルム和光純薬株式會社(wako) W01COBQV-4395
6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
17659-49-3 25g ¥160000 2024-03-01 購入
富士フイルム和光純薬株式會社(wako) W01COBQV-4395
6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
17659-49-3 250mg ¥144000 2018-12-26 購入

α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 化學特性,用途語,生産方法

説明

Amisodamine is a kind of alkaloid which is mainly living in anisodus tanguticus, which is a M receptor just like Atropine. It is a kind of traditional Chinese medicine which comes from the “National assembly of Chinese Herbal medicine”, and it is the alias of zangjia registered in “Chines herbal medicine summary of shan gan ning qing”. It is a perennial root herb that lives in the bottom slope in the eastern Tibet, Qinghai Province, the Southern GanSu Province, the western SiChuan Province, the northwestward YunNan Province. Since the sources is scare, racemic form of raceanisodamine is the main drug in clinic.

物理的性質(zhì)

Appearance: raceanisodamine is a kind of white crystal and crystalline powder. It is odorless and bitter to the taste. Solubility: it is easy dissolubility in hydrochloric acid and ethyl alcohol and is soluble in water. Melting point: it’s melting point is from 103 to 113?°C.?The weld spacing is within 6°. Specific optical rotation: ?9° to +11°.

來歴

It is the traditional Chinese medicine and the rich folk herbs that create favorable conditions to look for and develop good medicine. Dated from ancient times, anisodus tanguticus used to the treatment of pain. Unfortunately, it can lead to atropine poisoning resulted from large dosage. When found the adverse effects, research made analysis and finally discovered six kinds of ramifications. Besides, they found two types alkaloid anisodamine and anisodine. Compared with atropine, anisodamen has one more hydroxy in tropic ring and named “654”.

使用

anticholinergic, antispasmodic

適応癥

Anisodamine is a kind of anticholinergic agent. The tablet and injection form are mainly used to relieve smooth muscle spasm, biliary spasm and AOIP in clinical practice. The eye drop is used to treat teenage pseudomyopia; raceanisodamine concomitant with other drugs to treat cluster headache syndrome, renal colic, infantile diarrhea, infantile jaundice hepatitis, infantile purpura, bronchopneumonia, etc.

薬理學

1. Cholinolytic effect. Anisodamine can block acetylcholine receptors. We always take it as a merely blocker of M receptor. In recent years, it turns out that anisodamine is also a blocker of N receptor.
2. Calcium antagonist effect. Anisodamine will put up Clacium antagonist effect when ischemia, oxygen deficit or other reasons result in irreversible damage and apoptosis. 3. Reduce the level of NO. 50 mg/L anisodamine can restrain lipopolysaccharide combined with vascular endothelial cells and promote the production of NO and over-dosage of NO is the pivotal pathologic mechanism of the toxic shock . Pretreatment with anisodamine can reduce the level of NO obviously when cells are damaged and remit toxicity resulted from over-dosage of NO. 4. Anti-oxygenation. anisodamine can restrain myocardial function damage resulted from pyrogallol obviously and can adjust the function of cardioid damaged by ROS .

臨床応用

Anisodamine is a new drug developed by Chinese scientists. It has been widely put into use in clinical practice such as slow reflow phenomenon of ST-elevation acute myocardial infarction patients with percutaneous coronary intervention, infusion leakage , neonatal sclerosis. At present, it is mainly used to dilate vessels, remove vasospasm, improve blood circulation, increase tolerance of ischemia hypoxia and reduce the probability of the surrounding tissue necrosis

α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 上流と下流の製品情報

原材料

準備製品


α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 生産企業(yè)

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α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル  スペクトルデータ(1HNMR)


17659-49-3(α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル)キーワード:


  • 17659-49-3
  • ANISODAMINE
  • α-(Hydroxymethyl)benzeneacetic acid 6-hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl ester
  • Tropic acid 6-hydroxy-3-tropanyl ester
  • LAnisodaMine
  • 6-Hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl 3-hydroxy-2-phenylpropanoate
  • ANISODAMINE
  • Racanisodamine, 98%, from Anisodus tanguticus
  • [(3S,5S,6S)-6-hydroxy-8-methyl-8-azabicyclo[3.2.1]octan-3-yl] (2S)-3-hydroxy-2-phenylpropanoate
  • Anisodamine Intermediate
  • Benzeneacetic acid, α-(hydroxymethyl)-, 6-hydroxy-8-methyl-8-azabicyclo[3.2.1]oct-3-yl ester
  • ANISODAMINE USP/EP/BP
  • Tropic Acid 6-Hydroxy-3-tropanyl Ester discontinued, see H942900
  • Hyoscyamine Sulfate Impurity 8
  • Anisodamine|||7β-Hydroxyhyoscyamine|||Raceanisodamine
  • α-(ヒドロキシメチル)ベンゼン酢酸6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル
  • 6-ヒドロキシ-8-メチル-8-アザビシクロ[3.2.1]オクタン-3-イル 3-ヒドロキシ-2-フェニルプロパノアート
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