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CAS No. : | 96-31-1 | MDL No. : | MFCD00008286 |
Formula : | C3H8N2O | Boiling Point : | No data available |
Linear Structure Formula : | (CH3)NHCONHCH3 | InChI Key : | MGJKQDOBUOMPEZ-UHFFFAOYSA-N |
M.W : | 88.11 | Pubchem ID : | 7293 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P501-P260-P314 | UN#: | |
Hazard Statements: | H373 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
W.R. Grace silica gel; at 150℃; under 26618.1 Torr; for 12h;Conversion of starting material; | The procedure in example-38 was exactly repeated except that for the charge 6.32 x10"3 mol N, N'dimethyl urea, 15 ml dimethyl carbonate and 400 mg W. R. Grace silica gel catalyst were added. After cooling to room temperature the reaction mixture was filtered to separate the catalyst. Analysis of reaction crude by LC showed conversion of N, N' diphenyl urea to be 91 % and selectivity to N-methyl methyl carbamate to be 98 %. | |
silica gel; at 150℃; under 26618.1 Torr; for 12h; | The procedure in example-38 was exactly repeated except that for the charge 6.32×103 mol N,N'dimethyl urea, 15 ml dimethyl carbonate and 400 mg W. R. Grace silica gel catalyst were added. After cooling to room temperature the reaction mixture was filtered to separate the catalyst. Analysis of reaction crude by LC showed conversion of N,N' diphenyl urea to be 91% and selectivity to N-methyl methyl carbamate to be 98%. |