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[ CAS No. 7466-54-8 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}

2D 3D

Chemical Structure| 7466-54-8

Chemical Structure| 7466-54-8

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Quality Control of [ 7466-54-8 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 7466-54-8 ]

SDS Specification

Alternatived Products of [ 7466-54-8 ]

Product Citations

Product Details of [ 7466-54-8 ]

CAS No. :	7466-54-8	MDL No. :	MFCD00014755
Formula :	C₈H₁₀N₂O₂	Boiling Point :	No data available
Linear Structure Formula :	-	InChI Key :	QMGXWNSSMGAHCA-UHFFFAOYSA-N
M.W :	166.18	Pubchem ID :	24051
Synonyms :		Chemical Name :	2-Methoxybenzhydrazide

Safety of [ 7466-54-8 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P233-P260-P261-P264-P271-P280-P302+P352-P304-P304+P340-P305+P351+P338-P312-P321-P332+P313-P337+P313-P340-P362-P403-P403+P233-P405-P501	UN#:
Hazard Statements:	H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 7466-54-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 7466-54-8 ]

[ 7466-54-8 ] Synthesis Path-Downstream 1~4

1
[ 5683-31-8 ]
[ 7466-54-8 ]
2-methoxy-N'-(3-(trimethylsilyl)propionoyl)benzohydrazide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56.6%		3- (trimethylsilyl)Propyne acid (195 mg, 1.37 mmol) was dissolved in dichloromethane (4 ml). Oxalyl chloride thereto (0.123 ml, 1.44 mmol), and stirred for 2 hours at room temperature was added a DMF (1 drop). The compound obtained in Example 132-2 thereto (228 mg, 1.37 mmol), triethylamine (0.229 ml, 1.64 mmol) and stirred overnight at room temperature added. After the reaction was washed with saturated brine by the addition of chloroform. Dried with magnesium sulfate, and the solvent was evaporated. The residue was purified by silica gel column chromatography (SNAP Ultra 25 g, hexane / ethyl acetate) to give the title compound (225 mg, 56.6%) as a white solid.

Reference： [1]Patent: JP2016/124812,2016,A .Location in patent: Paragraph 0263; 0265

2
[ 7466-54-8 ]
[ 34374-88-4 ]
C₃₃H₃₀N₆O₉ [ No CAS ]

Reference： [1]Chemical Communications,2016,vol. 52,p. 11088 - 11091

3
[ 103854-64-4 ]
[ 7466-54-8 ]
C₁₉H₁₇N₃O₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol; at 80℃; for 3h;	General procedure: 8-Methoxyquinoline-2-carbaldehyde (25, 0.534 mmol) was refluxedwith various substituted acylhydrazines (0.587 mmol, 1.1 eq) in ethanol(5-10 mL) to get acyl hydrazides of 8-hydroxyquinoline. After completionof reaction, quinoline acyl hydrazides were found as precipitateson cooling to -15 C. Precipitates were washed with coldethanol and dried under vacuum. These acyl hydrazides were used directlyfor one pot synthesis of 2,5-disubstituted-1,3,4-oxadiazole usingiodine/K2CO3 catalysed oxidative cyclization. To the acyl hydrazides(1.0 eq) in DMSO (5-10 mL), K2CO3 (3.0 eq) and iodine (1.2 eq) wereadded in sequence and refluxed at 110 C. After the completion, thereaction mixture was cooled and saturated solution of sodium thiosulfatewas added. The precipitates were collected and dried under highvacuum to get the respective compounds (33-50).

Reference： [1]Bioorganic Chemistry,2018,vol. 80,p. 591 - 601

4
[ 7466-54-8 ]
[ 228244-04-0 ]
(S)-2-[5-(2-methoxyphenyl)-4H-[1,2,4]triazol-3-yl]-pyrrolidine-1-carboxylic acid tert-butyl ester [ No CAS ]

Reference： [1]ChemMedChem,2020

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Isomers

Technical Information

? Acyl Group Substitution ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions ? Chan-Lam Coupling Reaction ? Complex Metal Hydride Reductions ? Friedel-Crafts Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Lawesson's Reagent ? Leuckart-Wallach Reaction ? Mannich Reaction ? Nomenclature of Ethers ? Petasis Reaction ? Preparation of Alkylbenzene ? Preparation of Amines ? Preparation of Ethers ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Ethers ? Specialized Acylation Reagents-Carbodiimides and Related Reagents ? Specialized Acylation Reagents-Ketenes ? Specialized Acylation Reagents-Vilsmeier Reagent ? Ugi Reaction ? Vilsmeier-Haack Reaction

Historical Records

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P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
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Physical hazards
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H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
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H310	Fatal in contact with skin
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H316	Causes mild skin irritation
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H371	May cause damage to organs
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H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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