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CAS No. : | 7292-71-9 | MDL No. : | MFCD00049326 |
Formula : | C8H8ClNO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | MGOUENCSVMAGSE-UHFFFAOYSA-N |
M.W : | 185.61 | Pubchem ID : | 290730 |
Synonyms : |
|
Chemical Name : | 2-Amino-2-(3-chlorophenyl)acetic acid |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | a) (RS)-2-Amino-2-(3-chloro-phenyl)-ethanolTo a stirred solution of lithium borohydride in THF (10.5 ml, 2 M solution) under an argon atmosphere was added dropwise chlorotrimethylsilane (5.34 ml). The resulting suspension was cooled to 0 0C and amino-(3-chlorophenyl)-acetic acid (2.0 g) was added portionwise. The ice bath was removed and stirring at r.t. was then continued for 16 h. The mixture was quenched by dropwise addition of methanol (15 ml) and then concentrated in vacuo. The residue was suspended in ethyl acetate and washed with 2 N aq NaOH. The phases were separated and the aqueous phase was extracted with ethyl acetate. The combined organic phases were dried over sodium sulphate and concentrated in vacuo to afford (RS)-2-amino-2-(3-chloro-phenyl)-ethanol (1.84 g, quant.) as a yellow viscous oil. MS (ISP): 174.2 ( [{37C1}M+H]+), 172.2 ([{35C1}M+H]+). |
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