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CAS No. : | 70500-72-0 | MDL No. : | MFCD04117979 |
Formula : | C9H7NO2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | DBSPUDKBNOZFMX-UHFFFAOYSA-N |
M.W : | 161.16 | Pubchem ID : | 10975787 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P280-P305+P351+P338-P310 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | In a round bottom, flask, 5.0 g of 7-hydroxyquinolin-2(1H)-one, 7.5 g K2CO3 and 25 ml DMF were taken at 25-35° C. and the reaction mixture was stirred for 30 minutes at 25-35° C. 5.20 g <strong>[29882-07-3]4-chloro-1,1-dimethoxybutane</strong> was added into the reaction mixture and stirred for 10 hours at 70-75° C. After completion of the reaction, the reaction mixture was cooled to 25-35° C. and added into water. The solid was filtered and washed with water and dried in a hot air oven at 45-50° C. to obtain compound of the Formula (Y). Yield: 80percent. | |
With tetrabutylammomium bromide; potassium carbonate; In dimethyl sulfoxide; at 20 - 70℃; for 20h; | [0123] Compound of Formula (XI) (35 g), K2C03 (30 g), TBAB (35 g), DMSO (245 mL), and Compound of Formula (XII) (39.8g) were sequentially added to a suitable flask at 20-40°C. The mixture was heated to 60-70°C and stirred for not longer than 20 hr. After the reaction was complete, H20 was slowly added and the resulting solution was stirred for 1 hr. After an hour, additional H20 was added. The mixture was then cooled to 0-10°C and stirred for another 2 hr. The mixture was filtered and dried. Dry Compound of Formula (XIII) (56.5 g) was isolated in 93.8percent yield with 83.26percent purity. |